Composite Resin Flashcards
What are the constituents of composite?
Filer particles (glass such as quartz or microfine silica)
Resin (Bis-GMA)
Photoinitiator (campherquinone)
Silane Coupling Agent
Low weight dimethacrylates (TEGDMA)
What are 6 properties of composite resin?
Aesthetic
bonds to tooth
biocompatible
radiopaque
high strength
high hardness
low setting shrinkage if used in correct increments
What are the filler particles in composite?
These are made of glass and can be microfine silica or quartz
Types of filler particles includeL
- microfine
- hybrid
- conventional
What happens as we increase the filler content of composite?
Increased hardness and decreased thermal expansion
What is the resin in composite?
Bis GMA that is a bifunctional molecule that allows carbon to carbon cross linking during polymerisation - it undergoes FRAP and composite hardens
What is the photo initiator?
Campherquinone - creates free radicals when activated by blue light which initiate the free radical addition polymerisation
What is the low weight dimethacrylates?
They alter material viscosity preventing it setting too fast
What is the silane coupling agent?
This is in composite to bind the resin and the filler particles together (instead of glass binding to water)
Describe how composite bonding works
Composite is a material that is composed of filler particles, resin (Bis-GMA), photo initiator, low weight dimethacrylates and a silane coupling agent
The composite is placed in the tooth and then blue light is used to activate the camperhquinone which produces free radicals which initiate a free radical addition polymerisation reaction within the resin (due to the carbon to carbon double bonds which crosslink forming larger molecule). the silane coupling agent bonds the resin and the filler together (instead of filler to water). The polymerisation reaction results in the hardening of composite
What is hybrid composite?
Composite with mixture of conventional and microfine particles - increases hardness of composite, strength, improved aesthetics, reduced thermal expansion
What is light cure?
This is where we use blue light to activate campherquinone (photoinitato) that produces free radicals that initiate free radical addition polymerisation
What is problem with composite?
Can use too large increments resulting in inadequate depth of cure = unreacted monomer can leech and irrigate the pulp
Can use too large increments and bind walls together which can result in polymerisation shrinkage and then can lead to micro leakage and early failure
What affects composite wear?
Finishing
Placement
Location
Cavity size and design
occlusion
Why cant we leave caries at ACJ?
Will reult in unsupported enamel and can lead to early breakdown of restoration
What size increments do we place?
2mm as this is depth of cure of composite