colours and conditions Flashcards
group 1 carbonate thermal decomposition
thermally stable so dont decompose
group 1 nitrate thermal decomposition
2MNO3 -> 2MNO2 + O2
group 2 carbonate thermal decomposition
MCO3 -> MO + CO2
group 2 nitrate thermal decomposition
2M(NO3)2 -> 2MO + 4NO2 + O2
NO2 observations
brown gas
toxic so must be done in fume cupboard
Li flame colour
red
Na flame colour
yellow
K flame colour
lilac
Rb flame colour
red/violet
Cs flame colour
Blue/violet
Be flame colour
no colour
Mg flame colour
no colour
Ca flame colour
brick red
Sr flame colour
crimson
Ba flame test
apple green
Cl colour in water and hexane
colourless, colourless
Br colour in water and hexane
yellow/orange, orange/red
I colour in water and hexane
brown, pink/violet
halogen disproportionation reaction with cold alkali
2NaOH + Cl2 -> NaClO + NaCl +H2O
halogen disproportionation reaction with hot alkali
6NaOH + 3Cl2 -> NaClO3 + 5NaCl + 3H2O
Chlorine mixed with water
Cl2 + H2O <=> HCl + HClO
HClO + H2O <=> ClO- + H3O+
reaction between KF and H2SO4
KF + H2SO4 -> KHSO4 + HF
reaction between KCl and H2SO4
KCl + H2SO4 -> KHSO4 + HCl
reaction between KBr and H2SO4
KBr + H2SO4 -> KHSO4 + HBr
2HBr + H2SO4 -> Br2 + SO2 + 2H2O