colours and conditions Flashcards

1
Q

group 1 carbonate thermal decomposition

A

thermally stable so dont decompose

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2
Q

group 1 nitrate thermal decomposition

A

2MNO3 -> 2MNO2 + O2

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3
Q

group 2 carbonate thermal decomposition

A

MCO3 -> MO + CO2

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4
Q

group 2 nitrate thermal decomposition

A

2M(NO3)2 -> 2MO + 4NO2 + O2

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5
Q

NO2 observations

A

brown gas

toxic so must be done in fume cupboard

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6
Q

Li flame colour

A

red

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7
Q

Na flame colour

A

yellow

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8
Q

K flame colour

A

lilac

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9
Q

Rb flame colour

A

red/violet

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10
Q

Cs flame colour

A

Blue/violet

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11
Q

Be flame colour

A

no colour

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12
Q

Mg flame colour

A

no colour

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13
Q

Ca flame colour

A

brick red

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14
Q

Sr flame colour

A

crimson

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15
Q

Ba flame test

A

apple green

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16
Q

Cl colour in water and hexane

A

colourless, colourless

17
Q

Br colour in water and hexane

A

yellow/orange, orange/red

18
Q

I colour in water and hexane

A

brown, pink/violet

19
Q

halogen disproportionation reaction with cold alkali

A

2NaOH + Cl2 -> NaClO + NaCl +H2O

20
Q

halogen disproportionation reaction with hot alkali

A

6NaOH + 3Cl2 -> NaClO3 + 5NaCl + 3H2O

21
Q

Chlorine mixed with water

A

Cl2 + H2O <=> HCl + HClO

HClO + H2O <=> ClO- + H3O+

22
Q

reaction between KF and H2SO4

A

KF + H2SO4 -> KHSO4 + HF

23
Q

reaction between KCl and H2SO4

A

KCl + H2SO4 -> KHSO4 + HCl

24
Q

reaction between KBr and H2SO4

A

KBr + H2SO4 -> KHSO4 + HBr

2HBr + H2SO4 -> Br2 + SO2 + 2H2O

25
reaction between KI and H2SO4
KI + H2SO4 -> KHSO4 + HI 2HI + H2SO4 -> I2 + SO2 + 2H2O 6HI + SO2 -> H2S + 3I2 +2H2O
26
test for ammonium ions
NH4+ + OH- -> NH3 + H2O | add sodium hydroxide and heat mixture. Gas makes damp red litmus paper blue
27
test for sulfate ions
Ba2+ + SO42- -> BaSO4 | add HCl and barium chloride solution. White precipitate
28
methyl orange colour
yellow in alkali | red in acid
29
phenolphthalein colour
red in alkali | colourless in acid
30
thermal cracking conditions
1000*C 70atm
31
catalytic cracking conditions
zeolite catalyst slight pressure 450*C
32
ctatlyst used in reformation
platinum
33
catalytic converter equation
2NO + 2CO -> N2 + 2CO2
34
adding hydrogen to alkenes
150*C with Nickel catalyst
35
alkenes to alcohols
steam at 300*C 60-70atm Phosphoric (V) acid catalyst
36
oxidation of alkenes
acidified potassium manganate(VII) purple to colourless alkene to diol
37
halogenalkane elimination
react with warm alkali (KOH) dissolved in ethanol heated under reflux. alkene water and potassium halide are products formed