Colligative Properties Flashcards
Define colligative properties
Colligative properties are those properties of a solution which depends entirely upon the number of particles of the solution contained in a known volume of a given solvent and not at all upon the nature of the solute.
What are the colligative properties that that can be exhibited by a solution??
1) Relative lowering of vapour pressure.
2) Osmotic pressure
3) Elevation of boiling point
4) Depression of freezing point
Lowering of vapour pressure by a non volatile solute
When a non volatile solute is dissolved in a liquid, the vapour pressure becomes lower than the vapour pressure of the solvent, when a solute is dissolved in a liquid, some of the total volume of the solution is occupied by the solute molecules and so there are fewer solvent molecules per unit area surface, as a result, solvent molecules vapourizes slower than if no solute were present.
Osmosis and Osmotic pressure
There is a natural tendency of solutes in a solution to diffuse from a higher concentration to a lower concentration so as to bring about a uniform distribution throughout. The phenomenon of the movement of particles of a solute from more Concentrated to a less concentrated solution so as to bring about ultimate uniform concentration throughout the bulk, is known as diffusion
Boiling point elevation by non - volatile solute
The boiling of a liquid is the temperature at which it’s vapour pressure becomes equal to the atmospheric pressure.
Depression of freezing point by volatile solute
Freezing point is the temperature at which solid and liquid states of a substance have the same vapour pressure.