Class Six Flashcards

1
Q

what is a redox reaction

A

a reaction in which the oxidation numbers of any of the reactants change

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2
Q

when an atom loses electrons, it undergoes..

A

oxidation (oxidation # increases)

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3
Q

when an atom gains electrons, it undergoes..

A

reduction (oxidation # decreases)

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4
Q

LEO the lion says GER

A

lose electrons = oxidation

gain electrons = reduction

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5
Q

what is a reducing agent

A

an atom that is oxidized in a reaction (loses electrons)

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6
Q

what is a oxidizing agent

A

an atom that gains electrons

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7
Q

what happens to the anode

A

it gets oxidized and its electrons travel to the cathode

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8
Q

where does reduction take place in a galvanic cell

A

at the cathode

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9
Q

if the cell voltage is positive, the reaction is..

A

spontaneous

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10
Q

if the cell voltage is negative, the reaction is..

A

non spontaneous

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11
Q

the more negative the reduction potential..

A

the weaker the reactant is as an oxidizing agent

the stronger the product is as a reducing agent

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12
Q

the more positive the reduction potential..

A

the stronger the reactant is as an oxidizing agent

the weaker the product is as a reducing agent

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13
Q

Nernst equation

A
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14
Q

free energy change equation for a redox reaction

A

delta G = - (n)FE

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15
Q

value of faraday

A

96,500 C

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16
Q

what is a concentration cell

A

galvanic cell with identical electrodes but different ion concentrations

17
Q

what is an electrolytic cell

A

it uses an external voltage source to create an electric current that forces a non spontaneous redox reaction to occur

18
Q

how do electrons move in galvanic cell

A

from the anode to cathode

19
Q

Faraday’s law of electrolysis

A

the amount fo chemical change is proportional to the amount of electricity that flows through a cell

20
Q

time based cell calculation formula

A

I = nF/t

21
Q

main difference between galvanic and electrolytic cells

A

electrolytic cells have an external power source (galvanic is spon)

22
Q

where does plating occur

A

at the cathode

23
Q

in a galvanic cell, the cathode is..

A

positive

24
Q

in an electrolytic cells the cathode is..

A

negative

25
Q

where does pitting occur

A

at the anode

26
Q

in a galvanic cell, the anode is..

A

negative

27
Q

in an electrolytic cell, the anode is..

A

positive

28
Q

what happens in alpha decay

A

alpha particle is emitted out of the parent (2 pro & 2 neu)

parents atomic number goes down by 2 and mass number goes down by 4

29
Q

beta - decay

A

when there are too many neutrons in the nucleus

converts neutron → proton which is ejected

atomic number is now 1 greater

30
Q

beta + decay

A

when there aren’t enough neutrons → converts proton into a neutron and a positron

atomic number is now 1 less

31
Q

electron capture

A

takes an electron from closest shell and uses it to convert proton → neutron

atomic number is reduced by 1

32
Q

gamma decay

A

relaxing from an excited state releases a gamma photon

does not change the identity of the nucleus

just an expulsion of energy

33
Q

what is the mass defect

A

mass of combined nucleus is less than the sum of the masses of all its individual nucleons

34
Q

positive mass defect

A

seen in stable nucleus

35
Q

Einstein’s equation for mass energy equivalence

A

E = (delta m)c2