citric acid cycle Flashcards
citric acid cycle takes place in…
the mitochondrial matrix
PCIKSSFMO
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Please
pyruvate
Can
citrate
I
Isocitrate
KEEP
a-ketoglutarate
Selling
succinyl-CoA
Sex
succinate
For
fumarate
Money
malate
Officer
oxaloacetate
Step 1
citrate formation
step 2
citrate isomerized to isocitrate
making isocitrate means…
water is removed and then added back into the reaction
step 3
a-ketoglutarate formation and CO2
in step 3 the first…
NADH is produced
rate limiting enzyme for the citric acid cycle
Isocitrate dehydrogenase
step 4
succinyl CoA and CO2 formation
step 4 reduces…
NAD+ to NADH
step 5
succinate formation
the only reaction to directly produce ATP is…
step 5 (GTP formation–> ADP)
step 6
fumarate formation
in step 6…
FAD is reduced to FADH2
step 7
malate formation
step 8
oxaloacetate formed again
in step 8…
NAD+ is reduced to NADH
the citric acid cycle produces…
3NADH, 2CO2, FADH2, GTP
Control points of the citric acid cycle
citrate synthase, isocitrate dehydrogenase, a-ketoglutarate dehydrogenase
CPCSIDKD
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citrate synthase
immediately dad
isocitrate dehydrogenase
knows dat
a-ketoglutarate dehydrogenase
inhibition occurs at steps…
pyruvate, 1, 3,4
inhibition at pyruvate
inhibited by ATP, acetyl-CoA, and NADH
inhibition at step 1
inhibited by ATP, NADH, succinyl-CoA, and citrate
inhibition at step 3
inhibited by ATP, NADH
inhibition at step 4
inhibited by ATP, NADH, and succinyl-CoA
steps requiring electron acceptors (PIKSM)
pyruvate, isocitrate, a-ketoglutarate, succinate, malate
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