Chpt. 5, Electrons Flashcards
light
electromagnetic radiation; a type of wave
wavelength
the distance from a point on a wave to the same point on the next wave; the symbol for wavelength is λ
frequency
the number of wavelengths that oscillate in one second; the symbol for frequency is ν
the speed of light
(3.00 x 108 m/s); this value of sometimes represented by the letter c
the relationship between the speed, frequency, and wavelength of a wave
λν = c
Planck’s constant
h is Planck‟s constant, 6.626 x 10-4 sec
frequency, wavelength, and the energy of light (in Joules)
E = hν; the energy of light is related to its color
line spectrum
the pattern of lines with different colors
orbitals
the circular paths that electrons travel around the nucleus
ground states
the lower energy orbitals that an electron can start in
excited states
the higher energy orbitals that an electron can move up to
how an electron moves up and down the orbitals:
- it starts in a low energy state called the ground state
- when energy is added, the electrons absorb it and jump to higher energy orbitals called excited states
- eventually, the electron loses its energy and returns to the ground state
- the energy that the electron loses is given off as light; the energy of the light that is given off is equal to the precise amount of energy that is needed to move up to the given orbital, and this precise energy corresponds to a specific line on the line spectrum
- because there are many spectral orbitals, there are many spectral lines given off when the electron jumps back to the ground state from each excited state; the summation of all these lines is what we observe as the line spectrum
the quantum numbers
principal quantum number (n)
angular momentum quantum number (l)
magnetic quantum number (m-subscript-1)
spin quantum number (m-subscript-2)
principal quantum number (n)
determines the energies of the electrons in an atom; possible values are 1, 2, 3, etc
angular momentum quantum number (l)
determines the type of orbital that the electrons are located in; possible values include, 0, 1, 2, 3, etc, up to and including n-1; for example, if n = 3, the values of L are 0, 1, and 2
the value l = 0 corresponds to an s-orbital
l = 1 corresponds to a p-orbital
1 = 2 corresponds to a d-orbital
1 = 3 corresponds to an f-orbital