Chp 6 starts with cell theory Flashcards
What makes carbons tetravalnce shell so important to Chemistry
Carbon has 4 Ve- so it can covalently bond with up to four other atoms / molecules. This allows carbon to branch off and create complex molecules.
Define Tetravalence
Tetravalence - Is when an atom has 4 electrons in its valence shell.
C & C Inorganic and Organic Chemistry
Organic chemistry is said to be the study of compounds containing carbon.
Describe and illustrate length of carbon chains
Carbon chains i dont think have a limit and vary between molecules
Describe the arrangement of double bonds between carbons
dbl bonds which vary in number and location
What is the Hydrolysis rxn?
Hydrolysis is the addition of water to break down a polymer by a single monomer at a time
HO-(1)-(2)-(3)-(4)-H + H2O
H2O is used to attack the bond between 3 & 4 thus breaking it into a polymer with a monomer.
HO-(1)-(2)-(3)-H + HO-(4)-H
Dehydration or condensation rxn
This is when water is removed in the creation of a polymer from a monomer leaving water as a biproduct.
HO-(1)-(2)-(3)-H + HO-(4)-H –> HO-(1)-(2)-(3)-(4)-H +H2O
Define Monomers
Monomers are the repeating units tht serve as the building blocks to polymers and can be Carbohydrates. Proteins . Nucleic Acids
Define Polymers
A polymer is a LONG molecule consisting of many similar or identical building blocks linked together by covalent bonds. Consists of Carbohydrates , Proteins and Nucleic Acids.
Define Dimer
2 monomers attached together
What are the three classes of macromolecules tht consist of polymers
Proteins - is a biologically functional molecule made up of one or more polypeptides. Each folded and coiled into specific 3D shapes.
Carbohydrates - include sugars and polymers of sugars. the simplest carbohydrate is Monosaccharides. These are monomers from which more complex carbohydrates are formed. Disaccharides (2 bonded together. Polysaccharide many bonded together.)
Nucleic Acids - Are polymers made up of monomers called nucleotides. Nucleotides are composed of three parts : 5 carbon sugar AKA Pentose, Nitrogen-containing base, and one or more phosphate grps.
Define Polypeptide
A polymer of Amino Acids
Name the three monomers and what they do and the bonds associcated with them
1) The monomers of nucleic acids are nucleotides - is composed of a 5 carbon sugar called pentose, a nitrogenous-containing base, and one or more phosphate grps nucleotides to polynucleotides use dehydration rxn and are joined by phosphodiester linkage.
2) Of polysaccharides: monosaccharides. - Emperical formula oh CH2O Glucose is the most common monosaccharide. joined by glycosidic linkage. Glucose C6H12O6 with aldoses( C=O on the end of the chain) will form a ring with itself C1 attacks C5 OH. Carbon 5’s H on OH will be relocated to C1’s C=O making a single bond their. Then The newly fromed OH can attach itself with another glucose at its OH by dehydration making a glycosidic linkage.
3) Of polypeptides (the chains that make up proteins): amino acids. Amino Acids are Amino grp NH2 combined with a carboxyl COOH with a central C H2N-CRH-COOH they are joined together by the peptide bond. they link together by dehydration rxn with an H from NH2 and an OH from COOH.
What characteristics define lipids
1) they do not include true polymers
2) They are generally not big enough to be considered macromolecules
3) Compounds called liquids are grouped together because they mix poorly with water or if at all.
4) mostly consist of hydrocarbon regions.
5) lipids are varied in forms and function.
Name 3 types of lipids
Fats , Phospholipids and Steroids
Fats consist of….
two kinds of smaller molecules, glycerol and fatty acids.
Glycerol is an alcohol, each of its 3 C’s bears an OH
Fatty Acid has a long skeletal structure usually 16 C or 18 C in length. The carbon at one end is Carboxyl COOH which gives it the name fatty acid. the rest is hydrocarbons.
Phospholipids consists of….
Phospholipids are essential for cells because they r the major constituents of cell membranes. Glycerol has two fatty acids attached to it with a phosphate grp They now form bi layers two of these phospholipids come together with the hydrophobic ends in the middle and the hydrophilic ends on the outside. this makes up the outer shell of a cell.
Steroids consists of….
Steroids are lipids characterized by a carbon skeleton consisting of 4 fused rings. Cholesterol is a type of steroid. It is a common component of of animal cell membranes and is also the precursor from which other steroids, such as vertebrate sex hormones are synthesized.
Give the name of this functional grp as well as its function
-OH
Hydroxyl grp
Its polar due to O. It forms H-bonds w/ H2O helps dissolve compounds such as sugars
Give the name of this functional grp as well as its function
C=O
Carbonyl - sugars w/ ketone grps (C=O not at the end) are called ketoses. Sugars w/ Aldehyde grps (C=O at the end) are called aldoses.
Carbonyl grps are used to form rings within itself to make a more stable sugar. these r used to bond together other sugars called glycosidic linkage
Give the name of this functional grp as well as its function
COOH
Carboxyl - acts as an acid (it can donate H+) bcuz the covalent bond between O and H is polar.
they r used to form amino acids tht link together to form polypetides
Give the name of this functional grp as well as its function
NH2
Amino grp - acts as a base, it can pick up an H+ from surrounding solution
Help form polypeptides
Give the name of this functional grp as well as its function
-SH
Sulfhydryl grp - Two -SH grps can react, forming a cross link tht helps stabilize protein structure. (Hair protein,