(Chloromethyl) Benzene Flashcards
Alkaline hydrolysis of (chloromethyl) benzene
Reagent : NaOH(aq)
Condition : reflux
Product : CL - - > OH ( Alcohol) and Cl-
Formation of Nitrile for ( Chloromethyl) benzene
Reagent : KCN
Condition : ethanolic, reflux
Product : nitrile and Cl-
Reduction of nitrile
Reagent : H2
C : Ni and 180
P: Amine
Acidic hydrolysis of Nitrile
Reagent : H2O and H+
P: COOH and NH4+
Alkaline hydrolysis of nitrile
R: H2O and OH-
P : COO- and NH3
Formation of amine
R : NH3
C: ethanolic, conc, reflux
P : amine
Reaction with Cl2
1. Free redial substitution
R : Cl2
C : UV, reflux
P : throw H and add Cl
Electrophilic substitution of (chloromethyl) benzene
R: Cl2
C: FeCl3 (catalyst)
Product : ortho and para and HCl
Oxidation of chloromethylbenzene
R : KMnO4
C: acidified, reflux
P : benzoic acid and HCl
R : KMnO4
C : alkaline
P : benzoate