chemistry term 2 [exam] Flashcards

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1
Q

What are the 4 factors effecting rate of reaction

A

Agitation
Sub-division
Concentration
Temperature

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2
Q

Describe Agitation

A

Mixing + stirring reaction mixture (speeds up), exposes unreacted particles, removes build-up of solid/bubbles covering reactant

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3
Q

Describe Sub-division

A

Cutting up reactant exposing additional surface area, increase frequency of collision per second, smaller particles = faster reaction rate

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4
Q

Describe Concentration

A

As concentration increases, more particles in given volume, more particle collisions per second

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5
Q

Describe Temperature

A

Increases the number of collisions per second, increase the amount of energy the particles have.

Particles at a higher temp have more kinetic (moving) energy. = higher frequency of collisions

When particles have more kinetic energy, greater % of collisions will have sufficient energy to be successful. Therefore, increase in reaction rate.

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6
Q

Describe collision theory

A

Particles must collide with a favourable orientation and have sufficient energy to break existing bonds (activation energy).

Insufficient energy and the particles bounce off each other, sufficient energy and they will react. If incorrect orientation (e.g. oxygen -> oxygen) no reaction, correct orientation (e.g. carbon -> oxygen) reaction occurs.

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7
Q

When measuring reaction rates what does decrease in mass reflect

A

reflects change in reactants or products
The slope of the graph reflects the rate of the reaction:
 high gradient = fast reaction
 low gradient = slow reaction

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8
Q

When measuring reaction rates what does curve indicate

A

Curve indicates that the reaction rate is not constant but slows down/speeds up

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9
Q

Describe the structure of atoms in term of the electron shell

A

1st shell: Holds 2 electrons
2nd shell: Holds 8 electrons
3rd shell: Holds 18 electrons

The capacity of a shell formula: 2n2 [n = shell number]

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10
Q

What are valence electrons

A

The outer shell electrons.
e.g. Mg = 2,8,2 valence = 2
(no more than 8 in outer shell)

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11
Q

Explain periods

A

Periods (rows): Period number = number of electron shells

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12
Q

Explain groups

A

Groups (columns): Group number = number of valence electrons
(only applies to group 1,2,13,14,15,16,17,18)

Valence electrons is last digit of group.
E.g. group 13 = 3 valence electrons

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13
Q

In terms of metals, what is group 1

A

Alkali Metals

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14
Q

In terms of metals, what is group 2

A

Alkali Earth Metals

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15
Q

In terms of metals, what is group 17

A

Halogens

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16
Q

In terms of metals, what is group 18

A

Noble gases

17
Q

How many valence electrons in group 1

A

1 (Lose 1e-)

18
Q

How many valence electrons in group 2

A

2 (Lose 2e-)

19
Q

How many valence electrons in group 17

A

7 (Gain 1e-)

20
Q

What is the charge on ions in group 1

A

+1

21
Q

What is the charge on ions in group 2

A

+2

22
Q

What is the charge on ions in group 17

A

-1

23
Q

What are the properties in group 1

A

-Soft metal -Shiny when cut -Low melting point -Highly Reactive -React violently with water -Down the group, more reactive

24
Q

What are the properties in group 2

A

-Relatively soft -Low melting point -Very reactive -React with water -Down the group, more reactive

25
Q

What are the properties in group 17

A

-F and Cl are gases -Br is liquid -I and At are solids -Down the group less reactive

26
Q

What are the properties in group 18

A

-Stable arrangement -Full outer shells -Unreactive -Gases at room temperature