chemistry term 2 [exam] Flashcards
What are the 4 factors effecting rate of reaction
Agitation
Sub-division
Concentration
Temperature
Describe Agitation
Mixing + stirring reaction mixture (speeds up), exposes unreacted particles, removes build-up of solid/bubbles covering reactant
Describe Sub-division
Cutting up reactant exposing additional surface area, increase frequency of collision per second, smaller particles = faster reaction rate
Describe Concentration
As concentration increases, more particles in given volume, more particle collisions per second
Describe Temperature
Increases the number of collisions per second, increase the amount of energy the particles have.
Particles at a higher temp have more kinetic (moving) energy. = higher frequency of collisions
When particles have more kinetic energy, greater % of collisions will have sufficient energy to be successful. Therefore, increase in reaction rate.
Describe collision theory
Particles must collide with a favourable orientation and have sufficient energy to break existing bonds (activation energy).
Insufficient energy and the particles bounce off each other, sufficient energy and they will react. If incorrect orientation (e.g. oxygen -> oxygen) no reaction, correct orientation (e.g. carbon -> oxygen) reaction occurs.
When measuring reaction rates what does decrease in mass reflect
reflects change in reactants or products
The slope of the graph reflects the rate of the reaction:
high gradient = fast reaction
low gradient = slow reaction
When measuring reaction rates what does curve indicate
Curve indicates that the reaction rate is not constant but slows down/speeds up
Describe the structure of atoms in term of the electron shell
1st shell: Holds 2 electrons
2nd shell: Holds 8 electrons
3rd shell: Holds 18 electrons
The capacity of a shell formula: 2n2 [n = shell number]
What are valence electrons
The outer shell electrons.
e.g. Mg = 2,8,2 valence = 2
(no more than 8 in outer shell)
Explain periods
Periods (rows): Period number = number of electron shells
Explain groups
Groups (columns): Group number = number of valence electrons
(only applies to group 1,2,13,14,15,16,17,18)
Valence electrons is last digit of group.
E.g. group 13 = 3 valence electrons
In terms of metals, what is group 1
Alkali Metals
In terms of metals, what is group 2
Alkali Earth Metals
In terms of metals, what is group 17
Halogens