Chemistry Paper 2 Flashcards
What is the formula for calculating the rate of reaction in terms of reactant?
Mean rate of reaction = quantity of reactant used / time taken
What is the formula for calculating the rate of reaction in terms of product?
Mean rate of reaction = quantity of product formed / time taken
State the two units of measurement that reactants and products can be measured in.
By mass in grams or volume in cm3
What are the two possible units for rate of reaction?
g/s or cm³/s (where s is seconds)
What are the three possible units for rate of reaction?
g/s or cm³/s or mol/s (where s is seconds)
Susan carried out an experiment. 15g of product is made over 5 seconds. Calculate the rate of reaction.
15/5 = 3 g/s
Abdullah reacts magnesium with hydrochloric acid. The mass of the reactants decreases by 12.3 g over 3 seconds. Calculate the rate of reaction.
4.1 g/s
Natalie mixes two solutions together to produce a gas. 70cm3 of gas is produced in 3.5 seconds. Calculate the rate of reaction.
20 cm3/s
1 mol of gas is produced in 80 seconds when a solid is reacted with an acid. Calculate the rate of reaction.
0.0125 mol/s
State the 5 factors that affect the rates of chemical reactions.
1) Concentration of reactants in solutions
2) Pressure of reacting gases
3) The surface area of solid reactants
4) Temperature
5) Presence of catalysts
How does increasing the pressure of reacting gases affect the rate of reaction?
It increases.
How does decreasing the pressure of reacting gases affect the rate of reaction?
It decreases.
How does increasing the concentration of reactants in solution affect the rate of reaction?
It increases.
How does decreasing the concentration of reactants in solution affect the rate of reaction?
It decreases.
How does increasing temperature affect the rate of reaction?
It increases
How does decreasing temperature affect the rate of reaction?
It decreases.
How does increasing the surface area of solid reactants affect the rate of reaction?
It increases
How does decreasing the surface area of solid reactants affect the rate of reaction?
It decreases.
How does the presence of a catalyst affect the rate of reaction?
It increases
State the two conditions that need to be met in order for particles to react.
1) Particles must collide
2) They must collide with sufficient energy
Define activation energy.
The minimum amount of energy that particles must have to react.
Predict and explain the affect of increasing concentration on the rate of chemical reaction.
Reactions occur when particles collide with sufficient energy.
Increasing concentration means there are more particles in the same volume.
So there are more frequent collisions.
The rate of reaction increases.
Predict and explain the affect of increasing surface area on the rate of chemical reaction.
Reactions occur when particles collide with sufficient energy.
Increasing surface area exposes more particles.
So there are more frequent collisions.
The rate of reaction increases.
Predict and explain the affect of increasing temperature on the rate of chemical reaction.
Reactions occur when particles collide with sufficient energy.
When the temperature increases particles move faster with more energy.
There are more frequent collisions meeting the activation energy.
Rate of reaction increases.
Predict and explain the affect of decreasing pressure on the rate of chemical reaction.
Reactions occur when particles collide with sufficient energy.
Decreasing the pressure means less gas particles in the same volume.
So there are less frequent collisions.
The rate of reaction decreases.
What is a catalyst?
Something which changes the rate of a reaction but is not used up in that reaction
How do catalysts speed up reactions?
They provide a different route for the reaction to take place which has a lower activation energy.
The same catalyst can be used for many different reactions. True or false?
False.
What are enzymes?
Biological catalysts.
Many industrial processes use catalysts. Suggest why.
Catalysts provide a different route for the reaction to take place which has a lower activation energy.
Less energy is required.
Saves money.
How are reversible reactions different to reactions that go to completion?
In reversible reactions the product of the reaction can react to produce the original reactants.
By looking at a word or symbol equation, how can you determine if a reaction is a reversible reaction?
A reversible reaction will have a reversible arrow sign. ⇌
If a reaction is exothermic in the forward direction what will it be in the reverse direction?
Endothermic
Two reactants require 30kJ to turn into products. What energy transfer is involved when the products turn into reactants?
30kJ is released
What is equilibrium?
The point in a reversible reaction when the forward and reverse reactions are occurring at the same rate in a closed system.
How is the amount of reactant changing at equilibrium?
It is not changing
How is the amount of product changing at equilibrium?
It is not changing
What condition must be met in order for equilibrium to be established for a reversible reaction?
The reaction must take place in a closed system.
What is Le Chatelier’s principle?
When a reaction at equilibrium is changed, it will seek to counteract that change
N2(g) + 3H2(g) ⇌ 2NH3(g)
The above reaction occurs in a reaction mixture. Ammonia is removed from the reaction mixture. Explain the effect on the position of equilibrium.
Moves to the right hand side to produce ammonia.
To counteract the change.
2HCl(g) ⇌ H2(g) + Cl2(g)
The above reaction takes place in a reaction mixture. Hydrochloric acid is added to the reaction mixture. Explain the affect on the position of equilibrium.
Moves to the right hand side to produce hydrogen and chlorine.
To counteract the change.
2HCl(g) ⇌ H2(g) + Cl2(g)
The forward reaction is endothermic. Predict the effect of increasing the temperature on the amount of chlorine gas produced at equilibrium. Explain your answer using Le Chatelier’s Principle.
1) Amount of chlorine gas increases
2) Because system shifts to counteract the change
3) Because shifts to endothermic direction / shifts to take in energy
C2H4(g) + H2O(g) -> C2H5OH(g) ΔH = −45 kJ per mole
How would increasing the temperature change the YIELD of ethanol at equilibrium? Give a reason for your answer.
1) Increasing the temperature would lower the yield / equilibrium position moves to the left
2) Since the backwards reaction is endothermic / the forward reaction is exothermic
How does temperature affect the position of equilibrium?
Raising the energy of the system will shift it towards the endothermic reaction. Lowering it shifts it to the exothermic reaction.
C2H4(g) + H2O(g) -> C2H5OH(g) ΔH = −45 kJ per mole
How would increasing the pressure change the YIELD of ethanol at equilibrium? Give a reason for your answer.
1) Increasing the pressure would increase the yield / position of equilibrium moves to the right
2) Because the position moves in the direction of the lower number of moles of gas
2HCl(g) ⇌ H2(g) + Cl2(g)
Explain the effect of increasing the pressure on this equilibrium.
No change because there is an equal number of gas molecules on each side of the equation.
N2(g) + 3H2(g) ⇌ 2NH3(g)
The above reaction occurs in a reaction mixture. A low pressure is used in this reaction. Explain the effect on the yield of ammonia.
Decreases yield, because there are more moles/molecules of gas on the left hand side.
How does pressure affect the position of equilibrium?
Moves the position of equilibrium towards the side with less molecules.
What type of resource is crude oil?
It is a non-renewable finite resource.
What is crude oil made up of?
The remains of ancient biomass consisting mainly of plankton.
What is a finite resource?
One that will run out
Why is crude oil a finite resource?
Because we are using it faster than it is being produced.
What is a hydrocarbon?
A compound made of atoms of carbon and hydrogen only
Name the first four alkanes
Methane, ethane, propane, butane
What is the general formula for alkanes?
CnH2n+2
Most of the compounds in crude oil are what type of molecule?
Hydrocarbons
What is the formula of methane?
CH4
What is the formula for propane?
C3H8
Name the alkane with the formula C2H6
Ethane
Name the alkane with the formula C4H10
Butane
What is fractional distillation?
A process used to separate mixtures of substances with different boiling points
What are the steps involved in fractional distillation?
Crude oil is heated and vaporised.
Gas molecules rise up the fractionating column.
They condense at different points in the column as they have different boiling points.
Molecules with similar boiling points are separated within the same fraction.
The products of the fractional distillation of crude oil can be used for two main things. What are they?
1) Used as fuel
2) Feedstock for the petrochemical industry
Name four materials that are produced by the petrochemical industry.
Solvents, lubricants, polymers and detergents
Name five fuels we obtain from crude oil
Petrol, diesel, kerosene, heavy fuel oil and liquefied petroleum gases
What is a fuel?
A substance which when reacted with oxygen releases a large amount of energy
Complete the word equation: hydrocarbon + oxygen ->
hydrocarbon + oxygen -> carbon dioxide + water
During combustion, the carbon and hydrogen in hydrocarbons are reduced. True or False?
False, they are oxidised.
When does incomplete combustion occur?
When there is not enough oxygen present
How does boiling point change with the length of an alkane?
The longer the alkane, the higher its boiling point
How does viscosity change with the length of an alkane?
The longer the alkane, the more viscous (the thicker) it is
How does flammability change with the length of an alkane?
The longer the alkane, the less flammable it is
Write a balanced equation for the combustion of methane CH4
CH4 + 2O2 -> CO2 + 2H2O
What is cracking?
The process of breaking down a long hydrocarbon into smaller hydrocarbons
What are the products of cracking?
Short alkanes and alkenes
Why is cracking important?
Because it produces smaller hydrocarbons of which there is a greater demand because they are more useful than larger hydrocarbons.
How are alkenes different to alkanes?
Alkenes are more reactive than alkanes
How do you test for the presence of an alkene?
React with bromine water. Positive test will show colour change from bright orange to colourless.