chemistry paper 1 electrolysis Flashcards

1
Q

define electrolysis and an electrolyte

A

electrical energy from a direct current supply, decomposes electrolytes.

an ionic compound that’s molten or dissolved in water

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2
Q

electrode…

A

a rod made of a metal or
graphite which carries the current
into or out of the electrolyte

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3
Q

cations are positive ions and are attracted to…
anions are negative ions and are attracted to..

A

the negative cathode
the positive anode

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4
Q

reduction takes place at the..
oxidation takes place at the…

A

negative cathode
positive anode

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5
Q

electrolysis of dissolved salts is carried out using …
metal produced at..
non-metal produced at…
when molten salt is electrolysed

A

electrolysis
cathode
anode
ions r discharged as atoms or molecules at the electrodes

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6
Q

what products r formed at the anode and cathode during the electrolysis of copper chloride?

A

cathode - Cu2+ and H+ ions. Cu ions discharged mre readily. Brown solid

anode - Cl- and OH- ions. Cl ions dishcarged mre readily, cl forms as Pale green gas

Cop Cl decomposes but h20 no change

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7
Q

what porducts r formed at the anode and cathode during the electrolysis of sodium chloride

A

cathode - Na+ and H+ ions. H+ discharged more readily than sodium. Hydrogen gas formed

anode - Cl- and OH- ions , Cl ions discharge more readily than hydroxide. CL forms pale green gas

sodium chloride decomposes to form hydrogen and clhorine. Na and OH- ions remain in solution

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8
Q

what porducts r formed at the anode and cathode during the electrolysis of sodium sulfate

A

cathode - Na+ and H+ ions. H+ ions discharged more readily. Hydrogen gas forms.

anode - sulfate ions & OH- . OH- ions discharged more readily
than sulfate
ions, so oxygen gas is formed.

overall, water decomposes to form hydrogen and oxygen

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9
Q

what porducts r formed at the anode and cathode during the water being acidified w sulfuric acid.

A

Cathode: H+ ions are attracted. Hydrogen ions discharged forming hydrogen gas

Anode: SO4 2- and OH- ions attracted. Hydroxide ioms discharged more readily. Oxygen gas formed

overall: water decomposes to form
hydrogen and oxygen:
2H2O(l) → 2H2(g) + O2(g

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10
Q

How can electrodes be used to purify copper using copper electrodes?

A

-copper atoms in in anode loose electrons to become copper ions
-these dissolve in the solution and migrate to cathode where they r deposited as pure copper

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11
Q

list the reactivity series

A

potas , sod, calc, mag, alum, Zn, Iron, copp silver gold

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12
Q

which metals from the RS react with cold water to form hydrogen and a metal hydroxide?

A

potass, sodium ,calc

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13
Q

which metals from the RS react slowly w cold water but react w steam to form hydrogen and a metal hydroxide

A

mag, allum, Zn , iron

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14
Q

which elements dont react w hot or cold water or dilute acid from RS?

A

copper silver and gold

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15
Q

which elements from the RS react violently with dilute acid?

A

potass and sodium

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16
Q

which elements from the RS react w dilute acid to form hydrogen and a salt solution?

A

calc, mag , allum, Zn , iron

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17
Q

the higher up the metal in the RS…

A

the easily it looses electrons

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18
Q

what is extraction?
whats an ore?

A

a process where a metal is obtained from its ore
an ore is a rock that contains enough of a compound to extract a metal

19
Q

what method of extraction is used for potasssium to alumnium in the reactivity series?

A

electrolysis of a molten compound

20
Q

what method extraction can be used for zinc to copper in the RS

A

heat an ore with carbon

21
Q

what method of extraction can be used for silver and gold

A

non as its an uncombined element

22
Q

define bioleaching (a form of metal extraction)

define phytoextraction

A

using bacteria to extract metal from their ores

using plants to extract metal from their ores. Plants are burnt to form ash from which the metal is extracted

23
Q

adv and disadv of both bioleaching and phytoextraction

A

adv - no harmful gases produced, causes less damage to landscape than mining

very slow

24
Q

adv and disadv of just bioleaching

A

doesnt require high temps
toxic substances produced, damage to environ

25
Q

adv and disadv of just phytoextraction

A

can extract metals from contaminated soils
more expensive than mining some ores, growing plants depend on weather conditions

26
Q

what is oxidation and reduction in terms of oxygen?

A

oxidation is the gain of oxygen and reduction as the
loss of oxygen

27
Q

how do you obtain a metal from metal oxide cores?

A

oxygen is removed . Once removed the compound is said to be reduced

28
Q

define corrosion and rusting

A

when a metal reacts with oxygen (becomes oxidised) making the metal weaker over time.

rusting - the corrosion of iron or steel. H20 or 02 must be present

29
Q

why doesnt metals like aluminium rust?

A

their surfaces form a protective oxide layer which prevents further reaction

30
Q

what are advantages of recycling metals?
disadv

A

-natural reserves of metal ores will last longer
-less waste metals end up in landfill sites

-costs and energy using in collecting transporting and sorting metals

31
Q

what is a life cycle assessment and what are the 4 stages?

A

-its carried out to work out the environmental impact of a product and whether its worthwhile to manufacture and recycle the product
1. using the product
2. disposal of product
3. obtaining and processing raw materials
4. manufaturing and packaging the product

32
Q

most metals = transition metals and their typical properties are….

A

a high melting point
b high density
c the formation of coloured compounds
d catalytic activity of the metals and their compounds
as exemplified by iron

33
Q

what are reversible reactions? ⇌
dynamic equilibrium?

A

a reaction that works in both direction

when the forwards and backwards reactions in a reversible chem reaction are occuring at the same rate

34
Q

what conditions are needed for the haber process?

A

a temperature 450 °C
b pressure 200 atmospheres
c iron catalyst

35
Q

what is sacrificial protection

A

using a more reactive metal to prevent iron from rusting

36
Q

how is the position of a dynamic equilibrium
affected

A

a temperature
b pressure
c concentration

37
Q

describe the formation of ammonia

A
  • reversible reaction
    between nitrogen (extracted from the air) and hydrogen
    (obtained from natural gas)
    -it can reach a dynamic equilibrium
38
Q

what is electroplating? whys it used

A

using electricity to coat one metal with a thin layer of another metal
to improve its appearance; to improve its
resistance to corrosion/rusting

39
Q

define galvanising

A

coating iron or steel with a thin layer of zinc to improve its resistance to rusting
zinc improves corrosion resistance by stopping water reachin iron or steel (acting as a sacrificial metal)

40
Q

Explain why converting pure metals into alloys
often increases the strength of the product

A

making it into an alloy adds extra atoms which distorts the regular structure so the atoms can no longer slide over each other as easily making it less malleable

41
Q

what is an alloy
alloy steels are made by..

A

a mixture of metals
deliberately adding other elements to iron

42
Q

stainless steels…

A

resist rusting. it contains chromium that reacts with o2 in the air, creating a layer of chromium oxide thick enough to stop air and water reaching metal below

43
Q

how are aluminium copper and gold used

A