Chemistry In Society #2: Fertilisers Flashcards

1
Q

What do plants do when they grow?

A

They extract nutrients from the soil via their roots

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2
Q

What happens to plant soil over time?

A

The level of nutrients decreases and they need to be replaced

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3
Q

What do fertilisers, both natural and synthetic, do?

A

They allow farmers to increase the crop yield and farm intensely

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4
Q

What elements are essential for healthy plant growth?

A

Nitrogen, phosphorus, potassium

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5
Q

Nitrogen in fertilisers give

A

Nitrates and ammonium salts

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6
Q

Phosphorus compounds in fertilisers give

A

Phosphates

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7
Q

Potassium compounds in fertilisers give

A

Potassium salts

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8
Q

What is the Haber Process?

A

The industrial production of ammonia from nitrogen and hydrogen using an iron catalyst

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9
Q

Why can’t true equilibrium be achieved in the Haber Process?

A

It is a continuous process and an open system

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10
Q

What does the catalyst do in the Haber Process?

A

It provides a fast reaction rate and reasonable yield at lower temperature

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11
Q

Effect of temperature on the haber process

A
  • at lower temperatures, the forward reaction is too slow to be economical
  • at higher temperatures the rate of reaction increases but favours the reverse reaction
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12
Q

Effect of pressure on Haber Process

A
  • high pressure favours ammonia production but the required equipment is costly to build & maintain
  • compromises must be reached between the competing factors
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13
Q

How in the Haber Process made effective, and the temperature and pressure problems resolved?

A
  • maximum yield in the Haber Process requires high pressure + low temperature
  • the process is made effective using 200 atmospheres, 400 °c and an iron catalyst, giving about 15% yield
  • the ammonia produced is condensed and the unreacted gases are recycled reacting in and overall yield on 98%
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14
Q

What does maximum yield in the Haber process require?

A

High pressure and low temperature

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15
Q

How is the Haber Process made cost effective?

A

Using 200 atmospheres, 400 °c and an iron catalyst
= 15% yield

Ammonia produced is condensed and unreacted gases recycled
= 98% overall yield

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16
Q

Haber Process Equation

A

N2(g) + 3H2(g) ⇌ 2NH3(g)

ΔH = -92kJ (exothermic therefore -)

17
Q

What are the starting materials for the commercial manufacturing of nitric acid? (Ostwald Process)

A

Ammonia (Haber) and Oxygen

18
Q

What catalyst is used in the Ostwald Process? To give what yield?

A

Platinum, 98%

19
Q

Products of the Ostwald Process

A

Nitrogen monoxide, nitrogen dioxide, nitric acid

20
Q

Ammonia and nitric acid are important compounds used to produce what?

A

Soluble, nitrogen containing salts

21
Q

What happens to the backward reaction in Haber?

A

It is essentially cancelled as the unreacted gases are recycled

22
Q

Fertilisers are made by what reactions?

A

Neutralisation

23
Q

Ammonia + nitric acid -> ammonia nitrate

A

NH3 + HNO3 -> NH4NO3

24
Q

Ammonia + phosphoric acid -> ammonia phosphate

A

3NH3 + H3PO4 -> (NH4)3PO4

25
Q

Potassium hydroxide + nitric acid -> potassium nitrate + water

A

KOH + HNO3 -> KNO3 + H2O