chemistry for dose reduction Flashcards
define luminescence
light emission thats not caused by heating
define chemoluminescence
emission of light after a chemical reaction
define photoluminescence
when a chemical glows after being exposed to photos of light or x radiation
what is the difference between the electrons in an atom of gaseous and crystallin form?
gasesous:
- electrons have distinct separation between the orbits
- transitions known as Discrete
crystalline:
- electrons have energy levels which blur into bands
- making it easier for electrons to move between the levels
describe the type of energy band that insulators and semi conductors have + how it affects its function
insulators = energy band with large gaps need a lot of energy to move an electron between them
semi-conductors = energy band closer together need less energy
bands in contact or overlap can conduct electrons easily
how is coloured light formed when incident photon hits a bound electron
photon is absorbed and gives energy to electron
difference in energy bands between crystalline structures leads to colour sensitivity
or
emission of coloured light (when electron returns from higher state to original state releasing energy)
wavelength of energy causes colour (red for longer, blue for shorter)
why does each atom have specific coloured light emission
because in order for the emission to occur, the incident photon must have exactly the right energy to cause the electron energy level change
what does PSP stand for
photostuimuable storage phosphor
what is a light-emitting phosphor crystal / storage crystal
reacts to XR where electrons are given energy to change band
why is a latent image formed in light emitting phasor crystals
electrons are trapped in electron ‘holes’ within the crystal so they dont immediatly fall back into their lower state for ming the latent image (not yet visible)
where are PSP’s used and how
CR imaging, coating the plate inside the cassette
used to store image and retrieve it after
what are photostimuable phosphors made out of
barium attached to any halide to form e.g flurohalide, bromohalide
why do PSP’s contain europium
to dope it with holes in order to form the latent image by trapping electrons
what are the 8 layers of a CR plate
- front protective layer
- phosphor layer
- reflective layer
- electroconductive layer
- polyester base layer
- light shielding layer
- back protective layer