chemistry for dose reduction Flashcards

1
Q
A
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2
Q

define luminescence

A

light emission thats not caused by heating

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3
Q

define chemoluminescence

A

emission of light after a chemical reaction

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4
Q

define photoluminescence

A

when a chemical glows after being exposed to photos of light or x radiation

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5
Q

what is the difference between the electrons in an atom of gaseous and crystallin form?

A

gasesous:
- electrons have distinct separation between the orbits
- transitions known as Discrete

crystalline:
- electrons have energy levels which blur into bands
- making it easier for electrons to move between the levels

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6
Q

describe the type of energy band that insulators and semi conductors have + how it affects its function

A

insulators = energy band with large gaps need a lot of energy to move an electron between them

semi-conductors = energy band closer together need less energy

bands in contact or overlap can conduct electrons easily

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7
Q

how is coloured light formed when incident photon hits a bound electron

A

photon is absorbed and gives energy to electron

difference in energy bands between crystalline structures leads to colour sensitivity
or
emission of coloured light (when electron returns from higher state to original state releasing energy)

wavelength of energy causes colour (red for longer, blue for shorter)

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8
Q

why does each atom have specific coloured light emission

A

because in order for the emission to occur, the incident photon must have exactly the right energy to cause the electron energy level change

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9
Q

what does PSP stand for

A

photostuimuable storage phosphor

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10
Q

what is a light-emitting phosphor crystal / storage crystal

A

reacts to XR where electrons are given energy to change band

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11
Q

why is a latent image formed in light emitting phasor crystals

A

electrons are trapped in electron ‘holes’ within the crystal so they dont immediatly fall back into their lower state for ming the latent image (not yet visible)

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12
Q

where are PSP’s used and how

A

CR imaging, coating the plate inside the cassette

used to store image and retrieve it after

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13
Q

what are photostimuable phosphors made out of

A

barium attached to any halide to form e.g flurohalide, bromohalide

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14
Q

why do PSP’s contain europium

A

to dope it with holes in order to form the latent image by trapping electrons

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15
Q

what are the 8 layers of a CR plate

A
  • front protective layer
  • phosphor layer
  • reflective layer
  • electroconductive layer
  • polyester base layer
  • light shielding layer
  • back protective layer
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16
Q

why are phosphors preferably used

A

capturing image by turning xray into light is more efficient and lowers the dose to patient

17
Q

what are 2 commonly used phosphors used in each DR and CR

A

DR: CSi:Na (blue) , CsI:Tl (yellow)

Cr: BaFBr:Eu (blue), CsBr:Eu (blue)

18
Q

why is fluorescence used

A

live imaging

no delay

19
Q

describe process of fluorescence

A

incident photon removes bound electron from k-shell

higher energy electron fills the vacancy

as higher electron returns to ground state, it releases energy in form of light

20
Q

where is scintillation usee

A

in XR flat detectors (DR and flat panel fluroscopy)

21
Q

what are the advantages of scintillators

A
  • create high-resolution digital images at low dose
  • scintillator array phptodetectors are more sensitive tour than phosphorescent and fluorescent mechanisms
22
Q

describe the structure os scintillators and how this is an advantage

A

fine crystals grown for high resolution and minimal scatter of light between them

23
Q

where can scintillators be found

A
  • gamma cameras in NUCLEAR MEDICINE
  • very modern CT scanners
  • DR and Flat panel fluroscopy
24
Q
A