CHEMISTRY- ENERGY CHANGES IN INDUSTRY Flashcards

1
Q

What happens in exothermic reactions

A

Energy is released from reactants to surroundings
Temp of surroundings increases

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2
Q

What is the symbol for enthalpy change

A

Delta H

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3
Q

What happens in endothermic reactions

A

Energy takes from surroundings to reactions

Temp of surroundings decreases

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4
Q

Name diatomic elements

A

O2
H2
I2
Br2
Cl2
F2
N2

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5
Q

What is the standard enthalpy of combustion

A

Enthalpy change when 1 mole of a substance and it’s standard state burns completely in oxygen under standard conditions of 298k and one bar pressure.

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6
Q

Give an example of standard enthalpy of formation

A

H2 + 1/2 O —> H2O

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7
Q

What is the standard formation of water

A

L

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8
Q
A
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9
Q

What is the standard enthalpy of formation in their standard states

A

Zero

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10
Q

Why is the enthalpy of formation of Na zero

A

Na is an element in its standard state

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11
Q

State why the enthalpy of formation of liquid Na is not zero

A

Liquid is not sodium’s standard state

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12
Q

What is the standard enthalpy of formation

A

Enthalpy change when one mole of a substance is formed from its element under standard conditions of 298k and one bar pressure

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13
Q

What do standard enthalpies of combustion have

A

Almost always have negative values

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14
Q

Is burning a substance in oxygen exothermic or endothermic

A

Exothermic

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15
Q

What happens to substance that cannot be combusted

A

They have zero enthalpy of combustion

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16
Q

What types of substances cannot be combusted

A

Water
Carbon dioxide
And other oxides

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17
Q

Why may the enthalpy of combustion of a compound be difficult to measure

A

Incomplete combustion may occur

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18
Q

What do ions bond with

A

Water molecules

19
Q

What is the hydration of ions

A

The ions bond with water molecules
Positive ions will be attracted to the slightly negative oxygen in water molecules
Whilst negative ions will be attracted to the slightly positive hydrogens in water molecules

20
Q

What is Hess law

A

Reaction may have a very high activation energy
Reaction rate may be too slow
Possibility of competing reactions

21
Q

What is hess law used for

A

To calculate an enthalpy change indirectly

22
Q

name the type of reaction taking place when pentane burns in oxygen

A

combustion

23
Q

explain how exothermic processes affect their surroundings

A

releases heat from the system to the surroundings and the tempreture will increase

24
Q

state what is meant by the term standard enthalpy change of formation

A

when 1 mole of compound is formed from its elements under standard condition

25
state what is meant by the term enthalpy change of combustion
when 1 mole of a substance is combusted completely in oxygen
26
give one reason why the standard molar enthalpy change of formation of ethanol can not be measured directly
there are potentially other products and activation energy is too high
27
28
What is the definition of an enthalpy change?
The measure of heat given out or taken in during a process
29
Why is enthalpy change used instead of energy?
Because we cannot easily measure energy changes
30
Why is enthalpy easy to use?
They are measured under constant pressure That atmosphere is at a constant pressure, so we require no extra equipment
31
What type of enthalpy change does exothermic reaction have?
Negative
32
What type of enthalpy change does endothermic reaction have?
Positive
33
What is combustion?
An exothermic process that gives out heat
34
What are the standard conditions for enthalpy change
Pressure of one bar Temperature of 298 Kelvin Substances in its most stable state under the above conditions
35
What type of process is bond breaking?
Endothermic
36
What type of process is bond making?
Exothermic
37
What is the process used to extract aluminium from aluminium oxide?
Electrolysis
38
Explain why the structure of aluminium oxide makes the compound resist to high temperature
Because it has a strong intermolecular forces Has high, melting point Contains strong electrostatic forces between the ions Has a giant ionic structure
39
What is the temperature condition for Kelvin for standard conditions
298
40
What is the standard condition for pressure?
100 Kpa
41
Explain why the standard enthalpy change of formation for hydrogen gas is 0 kgMol-1
Hydrogen gas is an element on standard conditions so no change occurs
42
Name an organic compound that can be dissolved in water to manufacture hydrogen by electrolysis
Sodium chloride
43
State one use of short chain alkanes
Combustion
44
Explain how vanadium oxide acts as a catalyst
The vanadium oxide is regenerated by the end of the reaction Vanadium oxide is oxidised by oxygen