Chemistry - Chemical reactions and Energy Flashcards
What is an energy change?
-Almost every chemical reaction is accompanied by an energy change.
-When a chemical reaction happens, energy is transferred to or from the surroundings.
-Energy changes can be explained by examining the changes in chemical bonding during a reaction.
-Energy changes are used to classify reactions as exothermic or endothermic.
What is an exothermic reaction? Where are they used?
-An exothermic reaction happens when energy is transferred to the surroundings.
-During an exothermic reaction, the temperature of the surroundings increases.
-Exothermic reactions are used in self-heating food cans and outdoor hand warmers.
What is an endothermic reaction? Where are they used?
-An endothermic reaction happens when energy is taken in from the surroundings.
-During an endothermic reaction, the temperature of the surroundings decreases.
-Endothermic reactions are used in instant ice packs used to treat injuries.
What does an exothermic reaction graph look like?
-The products are at a lower energy level than the reactants.
-Energy is given out to the surroundings.
-The downwards arrow shows that energy is given out.
What does an endothermic reaction graph look like?
-The products are at a higher energy level than the reactants.
-Energy is taken in from the surroundings.
-The upwards arrow shows that energy is taken in.
What is a reaction profile graph?
-A reaction profile shows how the energy of the chemicals changes during a reaction.
-A reaction profile also includes the activation energy - the minimum energy needed to start a reaction.
-The activation energy is shown as a ‘hump’ in the line.
What is activation energy in a graph?
-Starts at the energy of the reactants
-Is equal to the difference in energy between the top of the ‘hump’ and the reactant.
What is the overall change in energy in a reaction?
-The overall change in energy in a reaction is still the difference between the energy of the reactants and the energy of the products.
How are bonds broken and made in a reaction?
-Energy is needed to break the bonds in the reactants
-Energy is released when the bonds in the products are formed
-The difference between the energy needed to break bonds and the energy released when forming bonds determines the type of reaction.
How do breaking and making bonds influence an exothermic reaction?
-More energy is released when new bonds are made than is needed to break existing bonds.
-The overall energy change is negative – meaning that energy is given out to the surroundings.
How do breaking and making bonds influence an endothermic reaction?
-More energy is taken in when the existing bonds are broken than is released in making new bonds
-The overall energy change is positive – meaning that energy is taken in from the surroundings
How do you calculate bond energies?
- Add together the bond energies for all the bonds in the reactants - this is the ‘energy in’.
- Add together the bond energies for all the bonds in the products - this is the ‘energy out’.
- Overall energy change = energy in – energy out.
Negative energy change = exothermic reaction
Positive energy change = endothermic reaction