Chemistry Flashcards

1
Q

Hund’s rule

A

states that electrons fill orbitals in a specific order, and they fill orbitals singly with similar spin before pairing

**Hund’s Rule. Hund’s rule: every orbital in a subshell is singly occupied with one electron before any one orbital is doubly occupied, and all electrons in singly occupied orbitals have the same spin.

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2
Q

Ionization energy is what?

A

energy necessary to remove an electron from a neutral atom in its gaseous phase

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3
Q

Electronegativity is what?

A

how easily an atom can attract an electrons and form chemical bonds

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4
Q

Melting point

A

amount of energy that is required to change the substance from a solid phase to a liquid

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5
Q

solute, solvent, solution, heterogenous, homogeneous, mixture

A

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6
Q

adhesive and cohesive

A

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7
Q

ionic substances actively dissolve in water, why?

A

because the hydrogen and oxygen atoms in the H2O molecules have partial charges that attract the ions in the solid compound, causing it to dissociate into separated ions. Differences in electronegativity account for the partial positive charge carried by water’s hydrogen atoms and the partial negative charge of its oxygen atoms. What is happening to the ionic compound when it dissolves is a separation of its ions from their preexisting solid crystal lattice structure into unattached ions that are free to move about in the solution.

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8
Q

tonicity

A

is a measure of the effective osmotic pressure gradient, as defined by the water potential of two solutions separated by a semipermeable membrane. In other words, tonicity is the relative concentration of solutes dissolved in solution which determine the direction and extent of diffusion. It is commonly used when describing the response of cells immersed in an external solution.
Unlike osmotic pressure, tonicity is influenced only by solutes that cannot cross the membrane, as only these exert an effective osmotic pressure. Solutes able to freely cross the membrane do not affect tonicity because they will always be in equal concentrations on both sides of the membrane. It is also a factor affecting imbibition.

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9
Q

hypertonic solution

A

those which have a higher concentration of a given solute than the interior of the cell. when placed in such solutions, the cell will lose solvent (water) as the solvent travels to area of higher solute in order to equalize concentrations

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10
Q

hypotonic solution

A

solution that has a lower concentration of a given solute than the cell. water will enter the cell causing it to swell.

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11
Q

isotonic solutions

A

those in which solute concentration equals solute concentration inside the cell

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12
Q

what is plasma?

A

similar to gas, but contains free moving charged particles (although its overall charge is neutral).

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13
Q

particles in gases, liquids and solids all do what?

A

vibrate

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14
Q

is energy being absorbed or released when particles go from solid to liquid?

A

going to higher energy state so energy is being absorbed (endothermic rxn)

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15
Q

is energy being absorbed or released when particles go from liquid to solid?

A

going to lower energy state so energy is being released (exothermic rxn)

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16
Q

melting

A

solid to liquid

17
Q

freezing

A

liquid to solid

18
Q

condensation

A

gas to liquid

19
Q

evaporation

A

liquid to gas

20
Q

sublimation

A

solid to gas

21
Q

deposition

A

gas to solid

22
Q

lines of equilibrium on a phase diagram?

A

any point on this line represents a pressure and temperature at which multiple phases exist in equilibrium

23
Q

triple point on a phase diagram?

A

the point at which the lines of equilibrium intersect and all three phases (solid, liquid, and gas) exist in equilibrium

24
Q

critical point on phase diagram? supercritical fluid

A

the point at which the phase boundary b/w liquid and gas terminates. This represents the fact that at very high temp and pressure, liquid and gas phases become indistinguishable. This is known as a supercritical fluid

25
Q

law of conservation of matter

A

that matter is neither created nor destroyed in a chemical reaction

26
Q

decomposition reactions

A

common class of reaction consisting of the separation of a compound into atoms or simpler molecules: AB –> A + B

27
Q

single substitution reactions

A

part of one molecule is replaced by another atom or molecule – reactivity is determined by activity series

AB + C –> AC + B

28
Q

combustion reaction

A

when oxygen is used as a reactant and produces carbon dioxide and water – produces a great deal of heat

29
Q

exothermic reactions

A

produce energy

30
Q

endothermic reactions

A

use energy

31
Q

regardless of whether energy is absorbed or released overall, every chemical reaction requires a certain amount of energy to begin. this is called what?

A

the activation energy

32
Q

a number of variables influence the rate of rxn

A

temperature, pressure, concentration, and surface area