Chemistry Flashcards
empirical formula
most reduced chemical formula
atomic number
number of protons in nucleus
mass number
number of protons + neutrons
isotopes
two atoms of the same element that differ in their number of neutons
alpha particle
2 neutrons and 2 protons, alpha decay subtracts 4 from the mass number and 2 from the atomic number
beta decay
adds 1 to the atomic number
positron emission
subtracts 1 from atomic number
emission spectrum
wavelengths of light emitted when electricity is run through a gas
diamagnetic
an atom that has all of its electrons spin-paired, it would have no magnetic field and be repelled by an externally produced magnetic field
exception to electron pairing rule
d orbitals want to be half filled or totally filled, can take an electron from s orbital
also all s electrons are lost before d electrons
atom in an excited state
has the same number of electrons but one is in a higher energy level
periodic trend: atomic radius
bottom left is largest
periodic trend: ionization energy
top right is largest
periodic trend: electron affinity
top right has highest affinity
periodic trend: electronegativity
top right is most electronegative
periodic trend acidity
bottom right is most acidic (based on the stability of the anion)
homolytic vs. heterolytic bond cleavage
homolytic - electrons are shared during split
heterolytic (dissociation) - electrons are taken by one atom
coordinate covalent bond
when an atom donates both its lone pair electrons to form a bond
Zeroth law of thermodynamics
like the associative property, if two systems are in thermal equilibrium with a third system, they are all in thermal equilibrium with each other
first law of thermodynamics
the total energy of the universe is constant, energy can not be created or destroyed
flow of energy statements
when energy flows into a system the energy of the surroundings decrease and when energy flows out of a system the energy of the surroundings increase
bonds and energy formation
energy is required to break bonds, energy is released when bonds are formed
isoelectric species
have the same electron configuration