Chemical Reactions part 1 Flashcards
Define chemical change
Reactants -> Products
Products have different properties to the reactants
Most are irreversible
Eg. Combustion reaction
Define physical change
The substance itself does not change, it just takes on a different form
Eg. Phase/State changes
Define rate of reaction
The change in concentration per unit of time of either the product or the reactant
Define collision theory
A reaction will only occur when an effective collision takes place. The more effective collisions take place per unit time, the faster the rate of reaction.
What are the 5 factors that affect the rate of reaction? Explain each.
- Increase concentration - Liquids
Increase number of particles, therefore increase number of collisions - Increase temperature
Particles have more energy -> Move faster -> More frequent collisions -> collisions have more energy - Decrease volume / Increase pressure - Gases
Particles are closer together, more collisions - Catalyst
Lowers activation energy - Increase surface area - solids
More area for particles to collide with, therefore more collisions
Explain temperature as a factor of affecting the rate of reaction.
As temperature increases, particles gain kinetic energy and move faster; which results in:
More collisions per second
More of the colliding particles have sufficient energy to react
Temp up, Rate of reaction up
Explain concentration as a factor of affecting the rate of reaction.
The higher the concentration, the more particles per unit volume
Results in more effective collisions per unit time and a faster reaction rate.
Explain catalyst as a factor of affecting the rate of reaction.
Def: A catalyst increases the rate of reaction and is unchanged at the end of the reaction
Mechanism: The catalyst decreases the activation energy of the reaction
Result: More collisions with be effective as more molecules collide with equal to or greater than the activation energy
More effective collisions lead to a faster reaction rate.
Explain surface area as a factor of affecting the rate of reaction.
Smaller the particle size -> greater surface area eg. powder vs chunks
Greater the surface area -> More surface exposed for the reaction to take place
Results in more effective collisions per unit time
Explain pressure as a factor of affecting the rate of reaction.
Increase pressure by reducing volume -> reduce space in which the gas particles can move
Results in more effective collisions per unit time and a faster reaction rate
What are the 2 methods of measuring the rate of reaction?
- Measure the volume of gas given off every minute
- Measure the decrease in mass of the reactant as the gas escapes