Chemical reactions Details Flashcards
Signs of a chemical change
-One or more new chemical substances are formed
-Energy is taken in/given out during the reaction
-Change is usually difficult to reverse
Signs of a physical change
-No new chemical substances are formed
-Change is usually easy to reverse
Factors which affect the rate of reaction
-Concentration
-Pressure
-Temperature
-Surface area(of reactants)
-Presence of catalyst
Why increased concentration increases the rate of reaction
-More particles per unit volume
-Higher collision rate
-Higher rate of reaction
Why increased pressure affects the rate of reaction
-Gas molecules are closer together
-Increased collision rate
-Increased rate of reaction
Why increased temperature affects the rate of reaction
-Particles have more energy and move faster
-Increased collision rate
-More particles have enough energy to start a reaction
-Increased rate of reaction
Why increased surface area affects the rate of reaction
-More particles exposed to other reactant
-Greater chance of particles colliding
-Increased collision rate
-Increased rate of reaction
Features of catalysts
-Increase the rate of reaction
-Is unchanged at the end of the reaction
-Decrease the activation energy of a reaction
A reversible reaction in a closed system is at equilibrium when…
-the rate of the forward reaction is equal to the rate of the reverse reaction
-the concentrations of reactants and products are no longer changing
Factors which affect the position of equilibrium(in a reversible reaction)
-Changing temperature
-Changing pressure
-Changing concentration
-Removing the product
Effect on yield if temperature is increased in a reversible reaction(forward reaction is exothermic)
temperature ↑ means yield ↓
Effect on yield if temperature is increased in a reversible reaction(forward reaction is endothermic)
temperature ↑ means yield ↑
If the pressure is increased(in a reversible reaction), the equilibrium moves…
in the direction of the fewest molecules of gas
When does a change in temperature shift equilibrium?
ALWAYS
When does a change in pressure shift equilibrium
When the reactants/products are gases and the number of molecules is different on each side of the equation