chemical quantities, reactions and equilibrium Flashcards

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1
Q

what is 1 mole

A

6.02 x 10*23 (which is avogadro’s number)

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2
Q

when was avogadro’s number (1 mole) developed

A

1811

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3
Q

in a calculation what do brackets suggest

A

that we have to multiply everything in the bracket by the number outside it

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4
Q

what is molar mass

A

this is the mass of a compound divided by the moles (g/mol)

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5
Q

how do we calculate molar mass

A

mass/ amount in moles (n)

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6
Q

how do we calculate mass

A

molar mass x amount in moles

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7
Q

how do we calculate moles

A

mass/ molar mass

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8
Q

what is concentration

A

the amount of a substance in a defined volume

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9
Q

what are the units of concentration

A

molarity (M)

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10
Q

how do you calculate concentration

A

molarity (M)= moles (mol)/ volume (L)

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11
Q

how do you calculates moles of a solution

A

molarity x volume

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12
Q

how do you calculate the volume of a solution

A

moles/ molarity

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13
Q

if you see a volume with ml as units what do you do

A

convert it into L by dividing it by 1000

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14
Q

what is the calculation for dilution

A

C1 x V1 = C2 x V2

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15
Q

what does C1 and V1 stand for

A

initial concentration and initial volume

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16
Q

what does C2 and V2 stand for

A

final concentration and final volume

17
Q

what is the calculation for initial concentration

A

C2 x V2/ V1

18
Q

what the calculation for initial volume

A

C2 x V2/ C1

19
Q

what’s the calculation for final concentration

A

C1 X V1/ V2

20
Q

what’s the calculation for final volume

A

C1 X V1/ C2

21
Q

what are reversible reactions

A

a reaction that can go forward and back

22
Q

what is an example of a reversible reaction

A

N2 + 3H2= 2NH3
2NH3= N2 + 3H2

23
Q

what is equilibrium

A

when a forward reaction equal to the rate of the reverse reaction

24
Q

what is the equation to represent equilibrium

A

rate F = rate R
(forward) (reverse)

25
Q

describe what happens at equilibrium

A

the rate of the forward reaction is equal to the rate of the reverse reaction. the conc is changing but the reaction isn’t stopped

26
Q

describe how equilibrium works for N2 + 3H2 = 2NH3

A

at the beginning of the reaction there is a lot of N2 and 3H2 and as the reaction continues the conc of N2 and 3H2 decreases. then the conc of 2NH3 increases. Finally, after dynamic equilibrium has been reached the concentrations don’t change anymore and the forward and reverse reactions are equal

27
Q

what is the calculation for equilibrium constants

A

Kc= [D]d [E]e / [A]a [B]b
(the products are on top and reactants are on the bottom)

28
Q

what does Kc show

A

shows the ratio of products and reactants at equilibrium

29
Q

when adding molecules into the equilibrium constant equation where do you place the coefficient (number in front of molecule)

A

make it an exponent (as a power, number at the top)

30
Q

what are the units of Kc

A

moles per litre

31
Q

when was le chatelier principle developed

A

1884

32
Q

what is le chatelier’s principle

A

if stress is applied to a system in dynamic equilibrium the system will be adjusted to relieve the stress

33
Q

what happens when the pressure is increased but the volume is decreased

A

this favours the side with fewer moles so equilibrium is moved to the right

34
Q

what happens when there is increased volume but decreased pressure

A

this favours the side with the most moles so equilibrium is moved to the left

35
Q

describe what temperature does to the equilibrium constant

A
  • when temperature changes so does Kc
  • when the forward reaction is exothermic (releases heat = temp decreases) the reverse reaction is endothermic (takes in heat= temp increases)