Chemical Equilibrium Flashcards

1
Q

the term refers to what we might call a “balance of forces”

A

equilibrium

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2
Q

occurs when a reaction and its reverse reaction proceed at the same rate.

A

Chemical equilibrium

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3
Q

A chemical reaction is in equilibrium when there is no tendency for the quantities of reactants and products to change.

A

Chemical Equilibrium

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4
Q

In a system at equilibrium, both the forward and reverse reactions are being carried out; as a result, we write its equation with a double arrow

A

Depicting Equilibrium

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5
Q

stem from the research by Cato Guldberg and Peter Waage (1864-1879)

A

Law of Mass Action

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6
Q

2 aspects of the Law of Mass Action

A

1) the equilibrium aspect
2) the kinetic aspect

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7
Q

concerning the composition of a reaction mixture at equilibrium

A

equilibrium aspect

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8
Q

concerning the rate equations for elementary reactions

A

kinetic aspect

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9
Q

is a dynamic process in which rates of reaction for the forward and backward reactions must be equal.

A

Chemical equilibrium

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10
Q

Gas-phase reactions that use units of partial pressure

A

Kp

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11
Q

Dissociation of water: dissociation constant of water

A

Kw

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12
Q

Dissociation of acids: acid dissociation constant

A

Ka

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13
Q

Reaction of bases with water: base dissociation constant

A

Kb

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14
Q

Solubility of precipitates: solubility product

A

Ksp

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15
Q

is a quantitative measure of the extent of reaction, the relative proportion of products and reactants present in the reaction mixture at some instant of time

A

Reaction Quotient (Q)

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16
Q

“If a system at equilibrium is disturbed by a change in temperature, pressure, or the concentration of one of the components, the system will shift its equilibrium position so as to counteract the effect of the disturbance.”

A

Le Châtelier’s Principle

17
Q

When the concentration of a product is increased, the reaction proceeds in reverse to decrease the concentration of the products.

A

Effect of Concentration

18
Q

In reactions where gases are produced, and increase in pressure will force the reaction to move to the left (in reverse).

A

Effect of Pressure