Chemical Equilibrium Flashcards
the term refers to what we might call a “balance of forces”
equilibrium
occurs when a reaction and its reverse reaction proceed at the same rate.
Chemical equilibrium
A chemical reaction is in equilibrium when there is no tendency for the quantities of reactants and products to change.
Chemical Equilibrium
In a system at equilibrium, both the forward and reverse reactions are being carried out; as a result, we write its equation with a double arrow
Depicting Equilibrium
stem from the research by Cato Guldberg and Peter Waage (1864-1879)
Law of Mass Action
2 aspects of the Law of Mass Action
1) the equilibrium aspect
2) the kinetic aspect
concerning the composition of a reaction mixture at equilibrium
equilibrium aspect
concerning the rate equations for elementary reactions
kinetic aspect
is a dynamic process in which rates of reaction for the forward and backward reactions must be equal.
Chemical equilibrium
Gas-phase reactions that use units of partial pressure
Kp
Dissociation of water: dissociation constant of water
Kw
Dissociation of acids: acid dissociation constant
Ka
Reaction of bases with water: base dissociation constant
Kb
Solubility of precipitates: solubility product
Ksp
is a quantitative measure of the extent of reaction, the relative proportion of products and reactants present in the reaction mixture at some instant of time
Reaction Quotient (Q)