chemical eqilibrium: equations Flashcards
what is the equation of the ionisation of water?
H2O (l) + H2O (l) => H3O+ (aq) + OH- (aq)
what does H3O+ (aq) represent in the ionsation of water equation?
what is a shorthand representation of H3O+ (aq)?
a hydronium ion (a hydrated proton)
H+ (aq)
what is the dissociation constant for the ionisation of water known as and what is it represented by?
ionic product (Kw)
what is the equation for the dissociation of water?
Kw=[H3O+][OH-]
the value of the ionic product varies w/ what?
temp
what is the value of Kw at 25C?
1x10^-14
give the equation of the relationship between pH and the hydrogen ion concentration
pH= -log10[H3O+] and [H3O+]=10^-ph
in water and aqueous solutions w/ a pH value of 7 the concentrations of both H3O+ (aq) and OH- (aq) are both what at 25C?
10^-7 mol l^-1
If the concentration of H30+ (aq) or the concentration of OH- (aq) is known, what can be used to calculate the concentration of the other ion?
Kw or pH +pOH=14
what is the acid dissociation constant represented as and give the equations?
-Ka
Ka=[H3O+][A-]/[HA]
OR BY
pKa where pKa=-log10Ka
what is used to calculate the approximate pH of a weak acid?
pH=1/2 pKa - 1/2log10c