chemical eqilibrium: equations Flashcards

1
Q

what is the equation of the ionisation of water?

A

H2O (l) + H2O (l) => H3O+ (aq) + OH- (aq)

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2
Q

what does H3O+ (aq) represent in the ionsation of water equation?

what is a shorthand representation of H3O+ (aq)?

A

a hydronium ion (a hydrated proton)

H+ (aq)

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3
Q

what is the dissociation constant for the ionisation of water known as and what is it represented by?

A

ionic product (Kw)

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4
Q

what is the equation for the dissociation of water?

A

Kw=[H3O+][OH-]

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5
Q

the value of the ionic product varies w/ what?

A

temp

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6
Q

what is the value of Kw at 25C?

A

1x10^-14

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7
Q

give the equation of the relationship between pH and the hydrogen ion concentration

A

pH= -log10[H3O+] and [H3O+]=10^-ph

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8
Q

in water and aqueous solutions w/ a pH value of 7 the concentrations of both H3O+ (aq) and OH- (aq) are both what at 25C?

A

10^-7 mol l^-1

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9
Q

If the concentration of H30+ (aq) or the concentration of OH- (aq) is known, what can be used to calculate the concentration of the other ion?

A

Kw or pH +pOH=14

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10
Q

what is the acid dissociation constant represented as and give the equations?

A

-Ka

Ka=[H3O+][A-]/[HA]
OR BY
pKa where pKa=-log10Ka

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11
Q

what is used to calculate the approximate pH of a weak acid?

A

pH=1/2 pKa - 1/2log10c

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