Chemical bonding Flashcards

1
Q

What are the 3 types of bonding for everything in the world

A

Ionic bonding (metal and non metal )
Covalent bonding ( nonmetals)
Metallic bonding ( silver surfer so think pure metal)

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2
Q

Ionic bonding definition

A

Electrostatic FOA between oppositely charged cations and anions

Explanation (no need) : Ionic bonds are formed when metal atoms transfer their valence electron to non metal atoms. This allow both to achieve stable electronic configuration of completely filled valence shells

THINK DOT AND CROSS DIAGRAM DO YOU KNOW HOW TO DRAW

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3
Q

What is the structure of ionic compounds

A

Giant ionic lattice structure with strong Electrostatic FOA between oppositely charged cations and anions

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4
Q

Properties of ionic compounds

A

High melting and boiling points

Conduct electricity only in molten and aqueous states

Hard and brittle

Soluble in water

Insoluble in organic solvents(methane)

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5
Q

Why do ionic compounds have a high m.p. and b.p.

A

Large amount of heat energy is needed to overcome the strong electrostatic FOA between oppositely charged ions

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6
Q

Why do ionic compounds only conduct electricity in aqueous and molten state

A

To conduct electricity the thing has to have mobile charge carriers

Ionic compounds do not conduct electricity in solid state as in this state the ions are held in fixed positions and so no free-moving ions to conduct electricity

but in aqueous and molten state –> there are free moving ions –> act as mobile charge carriers to conduct electricity

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7
Q

Why are ionic compounds hard and brittle

A

Hard: held tightly in fixed position in the lattice structure by strong electrostatic FOA

Brittle: With sufficient force, layers slide over one another causing ions of the same charge to be brought close together and they repel and the lattice structure breaks apart

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8
Q

Covalent bonding definition

A

A covalent bond is defined as the Electrostatic FOA between positively charged nuclei of atoms and their shared pair of electrons

Explanation: they share lah like two circles combine then got you dot dot in the middle

must know how to draw

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9
Q

What structures have covalent bonding

A

simple covalent/molecular structure

giant covalent structure

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10
Q

What bonding is in simple molecular structure

A

the molecule itself is held by strong covalent bond but why we call this simple is cause between the molecules got this weak as shit force called weak intermolecular forces of attraction(FOA)

since its weak easy to overcome thank goodness cause H2O has this structure which is why its a liquid

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11
Q

What are the properties of simple molecular structure

A

Low melting point and boiling point

Do not conduct electricity

soluble in organic solvents and insoluble in water

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12
Q

Why simple molecular structure got low mp and bp

A

relatively small amount of heat energy is needed to overcome these weak intermolecular FOA between molecules hence most exists as liquid and gases

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13
Q

Why do they no conduct electricity

A

simple they are electrically neutral and the only reason you see in movies that water shock people is cause that water is dirty and not pure so it contains ions which are mobile and so act as mobile charge carriers to conduct electricity

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14
Q

What are the 3 giant molecular/covalent structures you need to know everything about

A

Diamond
Graphite
Silicon dioxide (sand)

Note Diamond and graphite are allotropes of carbon

allotropes are different forms of the same element with different molecular structures

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15
Q

What is the structure and bonding of Diamond

A

Diamond has a giant molecular structure of a tetrahedral network of strong C-C single covalent bonds

Each C atom is bonded to 4 other C atom to achieve a fully stable configuration

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16
Q

Physical properties of Diamond

A

Hard : all atoms are held rigidly in place by strong covalent bonds

Hardest material so can use it for drills and saws

High melting point: Large amount of energy is needed to overcome all the strong C-C covalent bonds

Does not conduct electricity : all the valence electron in the carbon atoms are used for bonding as such there is no free moving electrons that can be delocalised to act as mobile charge carriers to conduct electricity

17
Q

Structure and bonding of Graphite

A

Graphite consists of flat layers of carbon atoms held together by strong C-C single covalent bonds arranged in hexagonal rings

There are weak intermolecular forces of attraction (van der Waals FOA) btw each layer of carbon atoms

18
Q

Physical properties of Graphite

A

Slippery: each layer of carbon atoms can slide past one another easily due to weak intermolecular forces of attraction (van der Waals )

So it can act as lubricant

High melting point: Large amount of energy is needed to overcome all the strong C-C covalent bonds

CAN conduct electricity:
Each carbon atom in graphite only uses 3 out of 4 valence electrons for bonding, so 1 electron per carbon atom can be delocalised to act as mobile charge carriers to conduct electricity

19
Q

Silicon dioxide not that impt

A

Si-O covalent bonds in a 3D tetrahedral arrangement each O atom bonded to 2 Si atoms

20
Q

Silicon dioxide properties

A

Hard

high mp

does not conduct electricity

ALL THE SAME AS DIAMOND

21
Q

Metals bonding and structure

A

Metals have a giant metallic structure which is made up of a lattice of metal cations surrounded by a sea of delocalised valence electrons

know how to draw

22
Q

Metallic bonding

A

electrostatic forces of attraction between cations and the sea of delocalised valence electron

23
Q

Properties of metallic structure

A

High mp and bp

can conduct electricty and heat

malleable and ductile

24
Q

Why does it have high mp and bp

A

large amount of thermal energy is needed to overcome the relatively strong electrostatic FOA between the metal cations and sea of delocalised valence electron

Except Group 1 metals and mercury

25
Q

Why can it conduct electricity

A

metals can conduct electricity in all states , the delocalised valence electrons are able to move freely to act as mobile charge carriers conduct electricity

note the higher the number of delocalised electron (eg group 2 metal each cation contribute 2 electron) the better the conductivity

it can gain heat well cause the delocalised valence electron are MOBILE and help in transfer the heat.

26
Q

why are metals malleable and ductile

A

malleable means able to be hammered into different shapes without breaking

ductile is can pull into wires

the reason for both these properties is when a force is applied the layers of metal ions are able to slide past each other and take new positions

27
Q

alloy

A

mixture of metal with other elements( to mess up everything)

28
Q

What are some physical properties of alloys

A

Varied mp and bp as its a MIXTURE

alloys good conductor of heat and electricity due to mobile ions acting as charge carrier

MOST IMPT : alloys are stronger and harder than pure metals as it contains atoms of different sizes which disrupt the orderly arrangement of atoms in the pure metal

so when a force is applied the layers of atoms cannot slide past each other easily