Chemical Bonding Flashcards
define chemical bond
the force which holds two or more atoms together in a stable molecule
periodic properties which affect chemical bond formation
- IP
- EA
- EN
for covalent compound, electronegativity difference…
should be negligible between the combining atoms
oxidation and reduction in terms of electrons
oxidation- loses electrons
reduction- gains electrons
define covalency
the number of electron pairs- which an atom shares with one or more atoms- of the same or different kind- to achieve stable electronic configuration
define polar covalent
when shared pair of electrons are unequally distributed between two atoms. charge separation takes place, and the atom which attracts electrons gets a slight negative charge.
define non polar covalent
when shared pair of electrons are distributed equally between two atoms. it is electrically neutral
formula of hydronium ion
H3O +
formula of hydroxyl ion
OH -
define coordinate bond
a bond formed by a shared pair of electrons with both electrons coming from the same atom. it has properties of both electrovalent and covalent bond. AKA dative/co-ionic bond
compounds containing ionic and covalent bond
sodium hydroxide
calcium carbonate
compounds containing covalent and coordinate bonds
carbon monoxide, nitric acid
compounds containing covalent, ionic, and coordinate bond
Ammonium chloride
K4[Fe(CN)6]
volatility of electrovalent and covalent compounds
ionic: non volatile
covalent: volatile
conduction of electricity of ionic and covalent compounds
ionic: solid- non conductors, liquid- conductors
covalent: non conductors
electrolysis of ionic and covalent compounds
ionic: can be electrolysed
covalent: only polar covalents can be electrolysed
why are ionic compounds soluble in water but not in organic solvents?
water has high dielectric constant (capacity to weaken force of attraction), while organic solvents have low dielectric constant
why are covalent compounds soluble in organic solvents but not in water?
organic solvents (non polar) dissolve non polar covalent compounds because like dissolves like. water cannot dissolve them because it is polar
difference between dissociation and ionisation
dissociation: separation of ions already present in compound, in ionic compounds
ionisation: formation of ions from molecules which are not in ionic state, in covalent compounds