chemical bonding Flashcards

1
Q

formal charge

A

total no of valence electron in the free atom - total no of non bonding electrons (lone pair)- 1/2 total no of bonding electron (shared)

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2
Q

PF3 obeys octect rule but PF5 doesn’t

A

due to presence of extra energy

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3
Q

examples of odd no compounds that doesn’t follow octect rule

A

NO and ClO2

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4
Q

electron deficient molecules

A

BeCl2, BF3, B2H6
behaves as lewis acids

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5
Q

bond enthalpy in CO,CN,N2,C2

A

CO>N2>CN>C2

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6
Q

dipole strength : NH3 OR NF3

A

NH3>NF3

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7
Q

what should be the size of the cation inorder to have large polaring power

A

smaller cation size and larger the anion

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8
Q

AX2 geometry

A

linear - BeCl2

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9
Q

AX3 geometry

A

triangular BF3

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10
Q

AX2E geometry

A

bent (V shape) SO2

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11
Q

AX4 geometry

A

tetrahedral CH4

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12
Q

AX3E geometry

A

triangular pyramidal NH3

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13
Q

AX2E2 geometry

A

bent H2O

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14
Q

AX5

A
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15
Q

AX4E

A

triangular bipyramidal PCl5

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16
Q

AX3E2

A

irregular tetrahedral ( see saw) SF4

17
Q

AX2E3

A

T shaped ClF3

18
Q

AX2E3

A

linear (I)3- (IODINE 3 - )

19
Q

AX6

A

octahedral SF6

20
Q

AX5E

A

square pyramidal BrF5

21
Q

AX4E2

A

square planar XeF4

22
Q

AX7

A

pentagonal bipyramidal IF7 (iodine)

23
Q

sp

A

linear,180, becl2, bef2, co2, ccs2, c2h2, [ag(cn)2]
hgcl2, hcn

24
Q

sp2

A

triangular planar, 120, bf3,bcl3,c2h4,no3-,so3,ch3+

25
Q

sp3

A

tetrahedral,109.28, sncl4,ch4,ccl4,sif4,nh4+

26
Q

dsp2

A

square planar,90, [ptcl4], [ni(cn)4]2-

27
Q

dsp3 or sp3d

A

trigonal bipyramidal, 120 and 90, pcl5,pf5,sbf5

28
Q

d2sp3 or sp3d2

A

octahedral,90,sf6,tef6,[crf6]3-,[co(nh3)6]3+

29
Q

d3sp3 or sp3d3

A

pentagonal bipyramidal,72 and 90, IF7

30
Q

read fingertips page 74

A