Biomolecules Flashcards

1
Q

Carbohydrates

A

Optically active polyleydroxy aldehydes or ketones

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2
Q

Monosaccharides example

A

Glucose, fructose, ribose

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3
Q

0ligosaccharides example

A

Sucrose, maltose

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4
Q

Polysaccharides example

A

Starch, cellulose, glycogen, gums
Non-sugars

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5
Q

Conditions for reducing sugars

A

Must reduce fehling’s solution and tollen’s solution
Eg: maltose, lactose
Non-reducing sugars: sucrose

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6
Q

Glucose from sucrose

A

Sucrose + water to give glucose + fructose with diLHCl or H2so4 in alcoholic solution

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7
Q

Glucose from starch

A

Hydrolysis of starch by boiling with dilute H2SO4

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8
Q

Glucose is Aldo or keto

A

Aldohexose and dextrose

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9
Q

Glucose + HI

A

N-hexane

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10
Q

Glucose +NH2OH

A

Oxime

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11
Q

Glucose +HCN

A

Cyanohydrin, presence of carbonyl group

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12
Q

Glucose + Br water

A

Gluconic acid
, presence of carbonyl group

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13
Q

Glucose + acetic anhydride

A

Glucose pentadcelate, 5 oh group

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14
Q

Glucose + nitric aced

A

Saccharic acid, presence of primary OH group

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15
Q

Alpha form of glucose is obtained by

A

Crystallization of concentrated glucose at 303K

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16
Q

Beta form of glucose

A

At 371 K

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17
Q

Anomers

A

Differ only by hydroxyl group in C1

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18
Q

Monosaccharides are joined by which bind to form disaccharides

A

Glycosidic bond

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19
Q

Sucrose composition

A

+ glucose and - fructose

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20
Q

Glycosidic linkage is present in which carbon atoms of sucrose

A

C1 of alpha glucose and C2 of beta fructose

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21
Q

Maltose composition

A

2 alpha glucose
C1 of one to C4 of another

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22
Q

Lactose composition

A

Beta D galactose and beta D glucose
C1 of galactose and C4 of glucose

23
Q

Components of starch

A

Amylose and amylopectin

24
Q

Amylose

A

Water soluble
15-20% of starch
Long unbranched
200-1000 alpha D glucose
C1-C4 glycosidic bonda

25
Amylopectin
Insoluble in water 85% starch C1-C4 glycosidic linkage beached chain polymer of alpha D glucose C1-C6 : branching
26
Cellulose
Polysaccharide of beta D glucose Glycosidic linkage between C1 and C4 carbon
27
Glycogen
Similar to amylopectin Highly branched
28
Proteins
Polymers of alpha amino acids
29
Essential amino acids
Alanine Glycine Glutamic acid Asparatic acid Tyrosine Serine cysteine Glutamine Asparagine Proline
30
Amino acid which is optically inactive
Glycine
31
Most naturally occurring amino acids have which configuration
L configuration
32
Peptide bond is formed between
Cooh and nh2
33
Insulin contains how many amino acids
51 amino acids
34
Fibrous proteins
Polypeptide chains runs parallel Insoluble in water Eg : keratin, myosin
35
Globular protein
Coiled structure Soluble in water Insulin and albumins
36
Proteins found in biological system with A unique 3 D structure and biological activity
Native protein
37
Denaturation of protein
Coagulation of egg white and formation of lactic acid
38
Almost all the enzymes are
Globular proteins
39
Fat soluble vitamin
A,D,E,K
40
Water soluble vitamin
B,C Can’t be stored except for vitamin B12
41
Vitamin A
Xeropthalmia Night blindness
42
Vitamin B1
Thiamine Beri-beri
43
Vitamin B2
Riboflavin Cheilosis
44
Vitamin B6
Convulsions
45
Vitamin B12
Pernicious anemia
46
Vitamin C
Ascorbic acid Scurvy
47
Vitamin D
Rickets and osteomalacia
48
Vitamin E
Increased fragility of RBC and muscular dystrophy
49
Vitamin K
Increased blood clotting time
50
Adenine
1 nh2 group , 1nh and zero O Double ring
51
Guanine
1 nh2 , 2nh and 1 =O Double rong
52
Cytosine
One =O and 1 nh2 group Single ring
53
Thymine
O nh2 and 1 ch3 group with 2=O Single rong
54
Uracil
0 nh2 group and 2 =O