Chemical Analysis (Paper 2) Flashcards

1
Q

What colour flame do lithium ions produce?

A

Crimson

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2
Q

What colour flame do sodium ions produce?

A

Yellow

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3
Q

What colour flame do potassium ions produce?

A

Lilac

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4
Q

What colour flame do calcium ions produce?

A

Orange - Red

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5
Q

What colour flame do copper ions produce?

A

Green

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6
Q

What colour precipitate do calcium ions produce?

A

White

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7
Q

What colour precipitate do copper ions produce?

A

Blue

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8
Q

What colour precipitate do iron(II) ions produce?

A

Green

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9
Q

What colour precipitate do iron(III) ions produce?

A

Brown

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10
Q

What colour precipitate do aluminum ions produce?

A

White at first but redissolves in excess NaOH to form a colourless solution

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11
Q

What colour precipitate do magnesium ions produce?

A

White

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12
Q

How do you test for chlorine gas?

A

Put damp litmus paper near / in the gas. If it bleaches, the gas is chlorine

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13
Q

How do you test for oxygen gas?

A

Put a glowing splint near / in the gas. If it relights, the gas is oxygen

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14
Q

How do you test for carbon dioxide gas?

A

Bubble the gas through limewater, if the limewater turns cloudy, the gas is carbon dioxide

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15
Q

How do you test for hydrogen gas?

A

Put the gas near an open flame, if you hear a squeaky pop, the gas is hydrogen

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16
Q

Define a pure substance

A

something that only contains one element or compound throughout

17
Q

Define formulations

A

mixtures created by humans with a specific purpose and specific amounts of each compound / element in them

18
Q

Define the mobile phase in chromatography

A

where the molecules can move. this is always a liquid or gas

19
Q

Define the stationary phase in chromatography

A

where the molecules can’t move. this can be a solid or a really thick liquid

20
Q

Define the Rf value in chromatography

A

the ratio between the distance travelled by the dissolved substance and the distance travelled by the solvent

21
Q

What is the equation for calculating the Rf value in chromatography?

A

distance travelled by substance / distance travelled by solvent

22
Q

What is the method for flame emission spectroscopy?

A
  • sample is placed in flame

- light released passes through spectroscope which detects light wavelengths to produce a line spectrum

23
Q

What is the purpose for flame emission spectroscopy?

A

to identify different metal ions in solutions accurately and find their concentrations

24
Q

How can flame emission spectroscopy identify different metal ions?

A

the combination of wavelengths emitted by an ion depends on its charge and electron arrangement so each ion has an individual combination of wavelengths. therefore each ion produces a unique line spectrum

25
What does the intensity of a line spectrum indicate?
the concentration of that ion in the solution
26
What is the test for carbonate ions?
using dilute hydrochloric acid and limewater - CO2 bubbles are produced and turn limewater cloudy
27
What is the test for sulfate ions?
forms insoluble white barium sulfate when mixed with dilute hydrochloric acid and dilute barium chloride solution
28
What is formed when silver ions react with halide ions?
insoluble precipitates
29
What colour precipitate is formed when chloride ions are mixed with silver ions?
white
30
What colour precipitate is formed when bromide ions are mixed with silver ions?
cream
31
What colour precipitate is formed when iodide ions are mixed with silver ions?
yellow
32
What is the test for halide ions?
add dilute nitric acid add dilute silver nitrate see which precipitates are formed