Chemical Analysis: Identifying Ions Flashcards
Lithium flame test result
crimson
Sodium flame test result
yellow
Potassium flame test result
lilac flame
Calcium flame test result
orange/red
Copper flame test result
green flame
Copper sodium hydroxide test result
blue precipitate
Iron (II) sodium hydroxide test result
green precipitate
Iron (III) sodium hydroxide test result
brown precipitate
Aluminium sodium hydroxide test result
white precipitate, dissolves in excess to form a colourless solution
Calcium sodium hydroxide test result
white precipitate
Magnesium sodium hydroxide test result
white precipitate
Describe the test for carbonate anions.
- Add dilute acid
- Fizzing/effervesence observed as CO2 is released
- Collect gas and bubble it through limewater
- Limewater goes cloudy
Describe the test for sulfate anions.
- Add dilute hydrochloric acid
- Add barium chloride solution.
- White precipitate forms
Describe the test for halide anions.
- Add dilute nitric acid
- Add silver nitrate solution
What are the results for the halide ion tests?
chloride - white precipitate
bromide - cream precipitate
iodide - pale yellow precipitate
Describe how to perform a flame test to identify metal ions.
- Clean a nichrome wire loop by holding it in a blue flame from a bunsen burner.
- Dip the loop into the sample you want to test and put it back in the flame.
- Record the colour of the flame.
What are the limitations of doing a flame test?
- only works for samples that contain a single metal ion
- if the sample tested contains a mixture of metal ions then the flame colours of som ions may be masked by the colours of others
What are the equations for the halide tests?
Ag+(aq) + Cl-(aq) → AgCl(s)
Ag+(aq) + Br-(aq) → AgBr(s)
Ag+(aq) + I-(aq) → AgI(s)
Whats the equation for the sulfate ion test?
Ba2+ + SO42-(aq) → BaSO4(s)
What are the advantages of using flame emission spectroscopy to identify ions?
- very sensitive - they can detect very small amounts of substances
- very fast
- very accurate