Bonding & Structure: Covalent Bonding Flashcards
What is a covalent bond?
A shared pair of electrons between two atoms.
What properties do simple molecular covalent substances have?
- do not conduct electricity
- low melting and boiling points
What is a simple covalent molecule in terms of its structure?
- contain only a few molecules (<100 atoms)
- held together by covalent bonds
Why do simple covalent molecules not conduct electricity?
They do not have any free electrons or ions.
Why do simple covalent molecules have low melting and boiling points?
Little energy is needed to overcome the weak intermolecular forces
What is strong in a simple covalent molecule, what is weak?
- strong covalent bonds between atoms
- weak intermolecular forces between molecules
How do intermolecular forces change as the mass/size of the molecule increases?
They increase
What do stronger intermolecular forces mean for a substance‘s melting and boiling points?
- increases melting and boiling points
- more energy needed to overcome these forces
What are giant covalent substances?
Atoms covalently bonded in a giant lattice (regular repeated structure)
What properties do giant covalent substances have?
- high melting and boiling points
- most dont conduct electricity (dont normally have delocalised e-
Why do giant covalent substances have high melting and boiling points?
They have strong covalent bonds which require a lot of energy to overcome.
What are some allotropes of carbon?
- diamond
- graphite
- fullerenes
- nanotubes
- graphene
What is an allotrope?
Different forms of an element that are bonded differently
Describe the structure of diamond.
- each carbon atom is joined to 4 other carbon atoms by strong covalent bonds
- the carbon atoms form a regular tetrahedral structure
- no delocalised electrons
Why is diamond very hard?
It has strong covalent bonds.