Chemical Analysis Flashcards

1
Q

In chemistry what is a pure substance

A

A substance made up of single element or compound, not
mixed with any other substances

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2
Q

In everyday language, what is a pure
substance

A

A substance that has had nothing added to it, in its
natural state

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3
Q

What are the boiling and melting points
like for pure substances

A

At a fixed (specific) temperature e.g. pure water would
boil at 100°C

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4
Q

What are the boiling and melting points
like for an impure (mixture) substances

A

Over a range e.g. salty water would boil from 100 - 105°C

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5
Q

What is a formulation

A

A mixture that has been designed as a useful product

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6
Q

How are formulations made

A

By mixing components in carefully measured quantities to get the required properties

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7
Q

Examples of formulations

A
  • Fuels
  • Cleaning agents
  • Paints
  • Medicines
  • Alloys
  • Fertilisers
  • Foods
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8
Q

A method used to separate dyes

A

Chromatography

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9
Q

What two phases are involved in
chromatography

A

Stationary and mobile phase

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10
Q

What is the stationary phase?

A

The chromatography paper

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11
Q

What is the mobile phase?

A

The solvent (usually water but can be any liquid e.g. ethanol)

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12
Q

What must you use when drawing the line
on the chromatography paper? Why?

A

Pencil
This is insoluble in the solvent so will not run

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13
Q

Where must the water be in relation to
the pencil line? Why?

A

Water line must be below the pencil line
To stop the inks mixing with the solvent

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14
Q

What does the distance the dots move tell
you?

A

How soluble the ink is in the solvent – if it moves to the
top it is very soluble

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15
Q

If the dot doesn’t move off the pencil line
what does that tell you?

A

The ink is insoluble in the solvent

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16
Q

Explain how the inks are separated using
paper chromatography.

A

Inks have different solubility’s
This means they move up the paper at different speeds/
distances

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17
Q

What is the Rf value

A

The ratio of the distance moved by a compound to the distance moved by the solvent

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18
Q

How can you express Rf Rf =

A

distance dot travelled ÷ distance solvent travelled

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19
Q

What value is Rf always below

A

1

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20
Q

How do we use the Rf values?

A

They are used to identify substances. Each substance has a specific Rf value so we use these to confirm what is in a mixture.

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21
Q

How many spots would you get for a pure
substance

A

One

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22
Q

How many spots would you get in a
mixture

A

More than one

23
Q

What is the test for hydrogen

A

Burning splint
Makes squeaky pop noise

24
Q

What is the test for oxygen

A

Glowing splint
Splint relights

25
What is the test for carbon dioxide
Bubble through limewater (calcium hydroxide solution)Limewater turns milky (cloudy)
26
What is the test for chlorine
Use damp litmus paper Turns bleached white
27
What test can be used to identify ions which produce a colour when burnt
Flame test
28
What metal ions produce distinctive colours in flame tests
Lithium Sodium Potassium Calcium Copper
29
What flame colour does lithium produce
Crimson red
30
What flame colour does sodium produce
Yellow
31
What flame colour does potassium produce
Lilac
32
What flame colour does calcium produce
Orange-red
33
What flame colour does copper produce
Green
34
Someone wants to identify a metal ion in a tablet, what must they do first?
Crush so in powder Or dissolve in water
35
What happens if there is a mixture of ions in a sample
Some flame colours can be masked
36
What hydroxide can be used to identify some metal ions in solution
Sodium hydroxide
37
What ions can be tested for using sodium hydroxide
Aluminium, Magnesium, Calcium, Iron (II), Iron (III), Copper (II)
38
What colour precipitate is formed for aluminium, calcium and magnesium with sodium hydroxide
White precipitate
39
How can you distinguish between aluminium, calcium and magnesium if they all form a white ppt with sodium hydroxide
Add excess sodium hydroxide Aluminium hydroxide precipitate will dissolve
40
What colour precipitate is formed with copper (II) and sodium hydroxide
Blue
41
What colour precipitate is formed with iron (II) and sodium hydroxide
Green
42
What colour precipitate is formed with iron (III) and sodium hydroxide
Brown
43
Half equation to show the formation of the blue ppt between copper (II) and sodium hydroxide
Cu2+ + 2OH- → Cu(OH)2
44
How do you test for a carbonate
React with a dilute acid Forms carbon dioxide gas Identified using limewater, goes cloudy
45
How do you test for a halide
Silver nitrate solution Presence of dilute nitric acid Precipitates form
46
What colour precipitate is formed between a chloride and silver nitrate
White precipitate
47
What colour precipitate is formed between a bromide and silver nitrate
Cream
48
What colour precipitate is formed between a iodide and silver nitrate
Yellow
49
How do you test for a sulphate
Barium chloride in the presence of dilute hydrochloric acid
50
What colour precipitate is formed between a sulphate and barium chloride
White
51
What are the advantages of instrumental methods
Accurate, More sensitive (can detect when have small amounts of the substance) Rapid Ease of use (operators don’t need chemical skills) Reliable/ efficient Sample doesn’t get used up
52
What instrumental method can be used to detect metal ions in solution
Flame emission spectroscopy
53
How is flame emission spectroscopy carried out
Sample is put in a flame Light given out is passed through a spectroscope The output is a line spectrum