Chemical analysis Flashcards

1
Q

What color flame does lithium ion produce

A

Crimson flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

What color flame does sodium ion produce

A

Yellow flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What color flame does potassium ion produce

A

Lilac flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

What color flame does calcium ion produce

A

Orange-Red flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

What color flame does Copper ion produce.

A

Green flame

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

What are two problems with flame tests?

A
  • The color of the flame can be difficult to distinguish. This could happen due to a low concentration of the metal compound.
  • Another reason is the sample could contain a MIXTURE of ions which mask the color of the flame
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

What is a better test than a flame test

A

A flame emission spectroscopy

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

How does an FES work

and the purpose

A

A sample of the metal ion in solution is placed in a flame

The light given out is then passed into a machine called a spectroscope

The spectroscope converts the light into a line spectrum

Since the positions of the lines in the spectrum are specific for a given metal ion.

So we can use this to identify the metal ion in the sample.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What two things does FES do

A

To identify the metal ion in the sample.

Tells us the concentration of the metal ion.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

Iron (III) Fe3+ions precipitates

A

Brown

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Copper (II) Cu2+ ion precipitates

A

blue

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Iron (II) Fe2+ ion precipitates

A

Green

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Magnesium Mg2+ ion precipitates

A

White

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Calcium, Ca2+ ion precipitates

A

White

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q

Aluminium Al3+ precipitate

A

White

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

How to distinguish between Aluminium ions from calcium ions and magnesium ions.

A

Add extra sodium hydroxide the aluminum hydroxide eventually will become colorless

If extra sodium hydroxide is added to calcium and magnesium the solution will not change.

17
Q

What is a formulation

A

A mixture that has been designed as a useful product

18
Q

Step 1 of testing for a Carbonate ion

A

Add dilute acid

19
Q

What will happen once Carbonate reacts with dilute acid

A

Carbon dioxide produced/created
Will see effervescence

20
Q

Chloride ions produce what precipitate. + colour

A

White precipitate of silver chloride

21
Q

Bromide ions produce what precipitate + colour

A

Cream precipitate of silver bromide.

22
Q

Iodide ions produce what precipitate + colour

A

Yellow precipitate of silver iodide

23
Q

What is the formula for the aqueous solution of lime water

A

calcium hydroxide

24
Q

How to test for carbon dioxide (5)

+ positive result

A

We test for co2 using limewater (lime water is an aqueous solution of calcium hydroxide)

Draw some of the gas in the test tube containing the possible co2 into a plastic pipette

We then bubble the gas through the limewater

Repeat several times

Positive result = lime water turns cloudy

Negative result = nothing happens

25
Q

How do we test for chlorine (3)

+ positive result

A

To test for chlorine we insert damp litmus paper into the mouth of the test tube.

Positive result: Chlorine bleaches the litmus paper and turns it white

26
Q

Testing for sulfate ions (3)

A

Add a few drops of HCl and add a few drops of dilute barium chloride

A white precipitate will form

27
Q

Explain why in a test for sulfate ions, the sample is acidified with hydrochloride acid first. (3)

A

Carbonate ions also produce a white precipitate with barium chloride solution. The acid reacts with any carbonate ions present. This removes them, so stopping them giving a false positive result

28
Q

How to test for halide ions (2)

A

Add a few drops of dilute nitric acid to the sample

Add a few drops of dilute silver nitrate solution