Chem - Quantum Flashcards

1
Q

S sublevel

A

1 s orbital, 2 electrons; spherical

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2
Q

P sublevel

A

3 p orbitals, 6 electrons; 2 lobes (dumbell)

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3
Q

D sublevel

A

5 d orbitals, 10 electrons; 4 lobes (clover)

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4
Q

F sublevel

A

7 f orbitals, 14 electrons; 8 lobes

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5
Q

Electromagnetic Spectrum

A

Series of waves that travel at the speed of light

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6
Q

Wavelength

A

The distance a wave travels in 1 cycle; the distance between corresponding points on adjacent waves

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7
Q

Frequency

A

Cycles per second; number of complete waves that pass a given point per second

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8
Q

Amplitude

A

Height or depth of a wave crest or trough, related to intensity of radiation or light

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9
Q

Wavelength and frequency

A

Inversely proportional, c = lambda × nu (c = speed of light)

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10
Q

Blackbody radiation

A

A solid object emits visible light when heated to 1000K, demonstrates that energy is related to frequency and wavelength

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11
Q

Energy and frequency

A

Directly proportional, E = h × nu (h = Plank’s constant

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12
Q

Quantum Theory of Energy

A

Any object can emit or absorb only certain quantities of energy

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13
Q

Quantum

A

A fixed quantity of energy

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14
Q

Photoelectric effect

A

The emission of electrons from a material when light of certain frequencies shines on the surface of the material, there must be a minimum or threshold frequency to cause the photoelectric effect

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15
Q

Photon

A

Bundle of energy

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16
Q

Atomic Emission Spectrum

A

A set of frequencies of electromagnetic waves given off by atoms of an element when they release energy as electrons return to a non-excited state; each element gives off a characteristic pattern

17
Q

Heisenberg Uncertainty Principle

A

It is impossible to know both the velocity and the position of a moving particle at the same time

18
Q

Quantum number: n

A

Energy level; positive integer

19
Q

Quantum number: L

A

Sublevel; ranges from 0 to n-1; s=0 p=1 d=2 f=3

20
Q

Quantum number: mL

A

Orbital; ranges from -L to +L

21
Q

Quantum number: ms

A

Spin; +/- 1/2 (upspin first)

22
Q

Paulu Exclusion Principle

A

An orbital can hold up to 2 electrons and they must have opposite spin

23
Q

Hund’s Rule

A

When filking orbitals of equal energy (same sublevel), each orbital receives one electron prior to pairing

24
Q

Aufbau Principle

A

Electrons enter orbitals of lowest energy first