Chem Lab Final Flashcards
Permanganate in acidic conditions
MnO4 - —–> Mn2+ (clear)
Permanganate in neutral conditions
MnO4 - —–> MnO2 (brown ppt)
Permanganate in basic conditions
MnO4 - ——> MnO4 2- (green)
Oxalate as a reducing agent
CO2 (see gas bubbles)
bisulfate (HSO3-) as reducing agent
becomes SO4 2- (sulfate)
oxidation numbers of halogens
-1 to +7
Strong oxidizing agent
- gains electrons more easily (is itself reduced)
- Usually X2 and turns into X-
- changes color the most
Strong reducing agent
- loses electrons more easily (is itself oxidized)
- usually turns from ion (X-) to X2
- most stable in color
EDTA CN and ox.no
ox no: -4
CN = 6 (hexadentate)
C2O4 CN and ox.no.
ox no: -2
CN = 2 (bidentate)
Co 2+
labile
Co 3+
inert
tetrahedral Co
pink
- stable at high temps
octahedral Co
blue
- stable at cold temps
transition metal CN
6
Reduction of Vanadium
(VO2) + —> (VO)2+. —>. (V)3+ —> V2+
Color of (VO2) +
yellow
Color of (VO)2+
blue
Color of V3+
green
color of V2+
violet
Naming complex ions (anything in [ ])
name ligands in alphabetical order then the central metal
- if it is an anion overall, name it the weird latin thing
Coordination Compounds
name cation and then anion
Dichromate
(Cr2O7) 2-
Chlorate
(ClO3)-
Hydrogen phosphate
HPO4 2-
Chlorite
(ClO2) -
Cyanide
CN-
Nitrate
NO3 -
Arsenite
(AsO3) 3-
Sulfate
SO4 2-
Phosphite
(PO3). 3-
bicarbonate
HCO3-
Oxalate
(C2O4) 2-
Chromate
(CrO4) 2-
Perchlorate
ClO4 -
Sulfite
(SO3) 2-
Hydroxide
OH -
Thiocynate
SCN -
Permanganate
MnO4 -
Carbonate
(CO3) 2-
Dihydrogen Phosphate
H2PO4 -
Arsenate
(AsO4) 3-
Phosphate
PO4 3-
Hypochlorite
ClO -
Nitrite
NO2 -
Accetate
CH3OO -
Ammonia
NH3
Ammonium
NH4 +
Strong Acids
1) HI: hydroiodic acid
2) HCl: hydrochloric acid
3) HBr: hydrobromic acid
4) HSO4: sulferic acid
5) HClO3: chloric acid
6) HClO4: perchloric acid
7) HNO3 : nitric acid
Hi - class - is boring - so - class over - class over - no I should go
Strong Bases:
1) LiOH: lithium hydroxide
2) NaOH: sodium hydroxide
3) KOH: potassium hydroxide
4) Ca(OH)2: calcium hydroxide
5) Sr(OH)2: strontium hydroxide
6) Ba(OH)2: barium hydroxide
7) RbOH: rubidium hydroxide
8) CsOH: cesium hydroxide
Like - Nathan - knows - California - is surely - bad -
- Rest in bed - after CS
What is a central metal in terms of electron pairs?
electron pair acceptor
What are ligands in terms of electron pairs?
electron pair donors