Chem Chpt 6 Test Flashcards

1
Q

How do you describe the flow of heat?

A

Heat always flows from an area of higher temperature to an area of lower temperature

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2
Q

Word to define randomness of a substance or system

A

Entropy

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3
Q

Word to define internal energy of a system plus the product of its pressure and volume

A

Enthalpy

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4
Q

What happens when water at 0 degrees Celsius changes to ice at 0 degrees Celsius?

A

Heat is released

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5
Q

What changes are expected to increase entropy?

A

Entropy increases when (spontaneity is positive)

Entropy decreases when (spontaneity is negative)

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6
Q

Name the device used to measure heat flow during physical processes or chemical reactions?

A

Calorimeter

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7
Q

Define energy

A

Energy: the ability to do work

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8
Q

Chemical reactions and physical changes that absorb heat are known as ______________.

A

Endothermic

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9
Q

The change in a system’s internal energy is the sum of heat added to the system and the work done on the system is the _____________ law of thermodynamics.

A

First law of thermodynamics

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10
Q

The field of chemistry that deals with energy changes in chemical reactions is chemical __________________.

A

Chemical thermodynamics

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11
Q

The thermodynamic state of a substance in its normal physical state at 1 atm and 298 K is the substance’s ________________.

A

Standard state

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12
Q

The SI unit of energy, whether heat or work, is the ________________.

A

Joule

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13
Q

Chemical reactions and physical changes that release heat are known as _____________ processes.

A

Exothermic

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14
Q

What is specific heat?

A

The heat required to raise the temperature of the substance 1 degrees Celsius.

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15
Q

What is standard enthalpy of formation?

A

For reactions in which one mole of a compound is formed from its elements in their standard states, the enthalpy change is called standard enthalpy of formation

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16
Q

What is heat vaporization?

A

Liquid changing into a gas

17
Q

What is heat of condensation?

A

Gas changing into a liquid

18
Q

What is heat of reaction?

A

The total amount of heat liberated or absorbed between the start of a reaction and its end, where all the products are at the original temperature of the reactants

19
Q

What is heat of crystallization?

A

Liquid turning into a solid

20
Q

What is heat of fusion?

A

A solid turning into a liquid

21
Q

In a certain experiment the temperature of the reactants is measured as 24.6 degrees celsious. After the experiment the temperature of the products is measured as 17.3 degrees celsious. This reaction is endothermic.

A

True

22
Q

At a constant pressure, enthalpy change equals heat.

A

True

23
Q

When a cup of water evaporates into water vapor the entropy change of the system is positive.

A

True

24
Q

The enthalpy of formation for any element in its standard state is negative.

A

False

Has an assigned enthalpy of zero

25
Q

According to the second law of thermodynamics the entropy of the universe is decreasing.

A

False

Entropy is increasing

26
Q

An endothermic reaction is characterized by a negative change in enthalpy.

A

False

Positive change in enthalpy

27
Q

The type of energy associated with position relative to a force is kinetic energy.

A

False

Potential energy

28
Q

Evaluate chemical evolution in light of entropy and chemical spontaneity.

A

Explain your answer

29
Q

When talking about thermodynamic concepts, the portion of the universe or sample of matter under study is the __________ and everything else is the ________________.

A

System

Surroundings

30
Q

Does 25 g of boiling water at 100 degrees Celsius or 25 g of steam at 100 degrees Celsius have more energy?

A

The 25g of steam water at 100 degrees Celsius