chem Flashcards

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1
Q

what do metals in groups 1,2,3 form

A

+1, +2, +3

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2
Q

what do non-metals in groups 5, 6, 7 form

A

-3, -2, -1

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3
Q

what are the first four orbitals called

A

S, P, D, F

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4
Q

what are s orbitals shaped like

A

they are shaped like a sphere

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5
Q

what are p orbitals shaped like

A

they are shaped like a dumb-bell

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6
Q

how many electrons can s orbitals hold

A

2 electrons

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7
Q

how many electrons can p orbitals hold

A

up to 6 electrons

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8
Q

how many electrons can d orbitals hold

A

up to 10 electrons

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9
Q

how many electrons can f orbitals hold

A

up to 14 electrons

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10
Q

where is the S block found

A

the first two groups of the periodic table

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11
Q

where is the D block found

A

transition metals (between S and P) in the periodic table

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12
Q

where is the P block found

A

on the right hand side of the periodic table (3-8)

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13
Q

where is the F block found

A

bottom 2 rows of the periodic table

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14
Q

what is a lattice

A

a regular 3 diensional pattern of ions

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15
Q

what are positive ions

A
  • generically formed by metal atoms losing elecrons and are found in groups 1,2 and 3
  • known as cations.
  • have a postive charge
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16
Q

what are negative ions

A
  • formed by non metal atoms gaining electrons.
  • have a negative charge
  • sometimes exists as polyatomic ions (OH-, CO3 2-) (SO4 2-)
  • known as anions
17
Q

what are covalent bonds

A

covalent bonds are formed when atoms share a pair of electrons

18
Q

what are metallic bonds

A

a strong electrostatic attraction between the positive metal and delocalised electron

19
Q

what are properties of metals

A
  • high melting and boiling point due to strong electrostatic attractions between positive and negative ions and electrons.
  • conducts electricity and heat due to delocalised electrons making them free to move.
  • malleability as layers of positive ions slides over each other and the delocalised electrons.
20
Q

what are intermolecular forces

A

interactions between molecules caused by either permanent/ induced dipoles.

21
Q

what are polar molecules

A
  • they have permanent dipoles because of the dipole interaction.
  • the molecules are attracted to eachother, these weak attracted forces are called permanent dipole-dipole interaction (chemical attraction)
22
Q

what is a london force

A
  • when electrons move around an atom, they cause an uneven distribution in the atom resulting in temporary dipole.
  • this will result in a weak attraction.
  • the more electrons, the more likely the process will occur so the stronger the London force.
23
Q

Why can only O, F and N atoms form hydrogen bonds

A

theyre small and highly electronegative (they pull pairs of electrons towards them)

24
Q

what bonds do water bonds form between each other

A
  • they form hydrogen bonds between each other.

- hydrogen bonds have strong intermolecular forces

25
Q

what do you have to remember when drawing hydrogen bonds between molecules

A
  • show the dipole charge on relevant atoms.
  • show the pairs of electrons on O, N or F.
  • indicate the hydrogen bond clearly eg using a dashed line.
26
Q

what is the relative formula mass

A

the sum of the relative atomic masses of all the atoms in the formula of the substance

27
Q

what is the formula for mole

A

mole= mass/ molar mass (relative formula mass)

28
Q

what is the reactivity series (from least reactive to most reactive)

A
  • lithium
  • sodium
  • potassium
  • rubidium
  • caesium
  • francium
29
Q

why does the reactivity increase in the reactivity series

A
  • the atoms get larger as you go down the group
  • the outer shell electron gets further away from the nucleus
  • the further the electron is from the positive nucleus, the easier it is to lose in a reaction
30
Q

what does a metal oxide + acid equal

A

salt + water

31
Q

what does a metal + acid equal

A

salt + hydrogen

32
Q

what are the rules for assigning oxidation numbers (the charge that the atom has)

A
  1. an element on its own has an oxidation number of zero
  2. for a simple ion, the oxidation number is the charge of the ion
  3. in a compound, the sum of the oxidation states is zero
  4. the sum of the oxidation numbers equals the charge on a complex ion
33
Q

what is the Avogadro’s law

A

equal volumes of different gases at the same pressure and temperature will contain equal numbers of particles

34
Q

how do you calculate the mass of a product when given the mass of a reactant

A
  1. calculate the number of moles of reactant (Mol= Mass/Mr)
  2. determine mole ratio of reactant to product: ensure the equation is balanced
  3. calculate the number of moles of the product:
    use the mole ratio
  4. calculate the mass of the product:
    (Mass=Moles x Mr)
35
Q

what is the formula for concentration

A

concentration= moles/ volume

36
Q

how do you go from kg to g

A

x 1000

37
Q

how do you calculate the percentage yield

A

actual yield/ theoretical yield X100