CHEM 1204 Test2 Flashcards

Carbohydrates and Lipids

1
Q

stereoisomers

A

molecules with the same structural formula but different 3 dimensional shapes

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2
Q

chiral

A

an object is chiral if it cannot be superimposed on its mirror image

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3
Q

an example of chiral

A

hands in a mirror

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4
Q

achiral

A

an object can be superimposed on its mirror image

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5
Q

enantimers

A

a chiral object and its mirror image make up a pair of enantiomers; also say that a chiral object and its mirror image are enantiomers of one another

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6
Q

chiral carbon atom

A

a carbon atom is chiral if it has 4 different things (atoms or groups) attached to it

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7
Q

a sugar that is a polyhydroxyl aldehyde (an aldehyde with an -OH group attached to every carbon with carbonyl group)

A

aldose

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8
Q

a sugar that is a polyhydroxyl ketone (a ketone with the carbonyl group on the 2nd carbon and the -OH group attached to all other carbons)

A

ketose

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9
Q

a way f representing a chiral molecule on a flat surface

A

Fischer projection

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10
Q

How to draw Fischer Projection

A

the chiral carbon atoms are not explicitly show; a chiral carbon atom occurs/exists at every intersection of 2 lines; carbon atoms that are not explicitly show are drawn vertically

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11
Q

Aldose Fischer

A

has a carbonyl group on the top carbon

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12
Q

Ketose Fischer

A

has a carbonyl group on the 2nd carbon from the top

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13
Q

carbohydrate

A

a polyhydroxy(-OH) aldehyde or ketone or substance that yields polyhydroxy aldehydes or ketones upon hydrolysis

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14
Q

-OH represents

A

a hydroxy group and an alcohol group

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15
Q

monosaccharide

A

a single sugar molecule

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16
Q

disaccharide

A

a molecule made of 2 monosaccharides

17
Q

polysaccharide

A

a molecule made up of many monosaccharides; some polysaccharides are made up of thousands of monosaccharides

18
Q

D form of glucose

A

the -OH group on the bottom chiral carbon points right

19
Q

L form of glucose

A

the -OH group on the bottom chiral carbon points left

20
Q

what is the geometry of a chiral carbon

A

tetrahedral

21
Q

dextrose

A

most important sugar that is the right glucose

22
Q

how many chiral carbons does glucose have

A

4

23
Q
# of chiral carbons : 1
# of Fischer projections: 
# of pairs of enantiomers
A
# of Fischer projections: 2
# of pairs enantiomers: 1
24
Q
# of chiral carbons : 2
# of Fischer projections: 
# of pairs of enantiomers
A
# of Fischer projections: 4
# of pairs enantiomers: 2
25
Q
# of chiral carbons : 3
# of Fischer projections: 
# of pairs of enantiomers
A
# of Fischer projections: 8
# of pairs enantiomers: 4
26
Q
# of chiral carbons : 4
# of Fischer projections: 
# of pairs of enantiomers
A
# of Fischer projections: 16
# of pairs enantiomers: 8