Chapters 11 And 12 Flashcards
Describe unsaturated FA
Has double bonds in carbon chain which creates kink in FA
Two type of unsaturated FA
Polyunsaturated
Monounsaturated
Monounsaturated vs polyunsaturated
Monounsaturated contain only 1 double bond
Most abundant saturated FA
Palmitic
Most abundant monounsaturated FA
Oleic
Most abundant polunsaturated FA
Linoleic and alpha linoleic
What determines the melting point?
3 factors
- Chain length
- Degree of unsaturation
- Configuration of double bond
How does chain length affect melting point
short-chained FA’s have lower melting points
Degree of unsaturation effect on melting point
unsaturated FA’s have lower melting points
Configuration of double bond effect on melting point
cis form has lower melting point than trans
What is rancidity
The chemical deterioration of a fat caused by the uptake of oxygen (oxidation) or water (hydrolysis).
Explain hydrolytic rancidity
•Fatty acids break off from glycerol by lipase
2 effects of hydrolytic rancidity
- Release volatile fatty acids
* Off flavors
What is acrolein
By product of hydrolytic rancidity during deep frying
Explain oxidative rancidity
- Heat, light, free radicals break down fatty acids ( most start with singlet oxygen)
- Creates chain reaction