Chapter Ten Flashcards

Energy changes in chemical reactions

1
Q

Where is chemical energy stored

A

In between the bonds between atoms and molecules

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2
Q

Chemical energy results from

A
  • Attraction between e- and p+ in atoms
  • Repulsions between nuclei
  • Repulsions between e-
  • Movement of electrons
  • Vibrations and rotations around bonds
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3
Q

What is the SI unit for energy

A

Joule

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4
Q

Additional SI units for energy

A
  • Kilojoules
  • Megajoules
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5
Q

What is the relationship between Kj, Mj and J

A

1 MJ = 1000kJ = 1 000 000 J

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6
Q

Law of conservation of energy

A

Energy cannot be created or destroyed but it can change forms

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7
Q

System

A

The chemical reaction

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8
Q

Surroundings

A

Usually regarded as everything that is not the chemical reaction

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9
Q

Energy leaves the… into the … or leaves the … into the …

A
  • Surroundings, system
  • System, surroundings
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10
Q

What determines whether energy is released or absorbed

A

The relative energies of the bonds within the reactants and products

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11
Q

Will separated particles have more or less energy than when they were together

A

More

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12
Q

What happens to the bond when energy is absorbed

A

The bond breaks

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13
Q

What happens to energy when bonds form

A

Energy is released

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14
Q

What forms does energy take

A
  • Heat
  • Light
  • Electricity
  • Kinetic
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15
Q

Endothermic reactions

A
  • Energy enters the system
  • The total chemical energy of the reactants is less than the products
  • Absorbs heat from surroundings so the environment becomes cooler
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16
Q

Exothermic reactions

A
  • Energy is released into the surroundings
  • Total chemical energy or reactants is more than the products
  • All combustion reactions give off heat energy to the surroundings
17
Q

Changes of state

A
  • Phase changes
  • Physical changes but still involves energy being released/absorbed
18
Q

Heat taken from environment =

A

Endothermic

19
Q

Heat released to environment =

A

Exothermic

20
Q

Enthalpy (H)

A

The stored chemical energy of a substance

21
Q

Enthalpy change/ heat of reaction (ΔH)

A

The exchange of heat between the system and its surroundings

22
Q

Enthalpy change in endothermic reactions

A
  • System has gained energy so ΔH is positive
  • ΔH > 0
23
Q

Enthalpy change in exothermic reactions

A
  • System has lost energy so ΔH is negative
  • ΔH < 0
24
Q

Where are the enthalpy changes written in thermochemical equations

A

To the right of the equation

25
Q

What units is enthalpy measured in

A

kJmol^-1

26
Q

How do you compare enthalpy changes

A

Compare equal quantities of the substance

27
Q

How is ΔH effected by reversing a chemical reaction

A

Reversing a chemical reaction changes the sign but not the magnitude of the ΔH (- or +)

28
Q

Activation energy

A

The energy required to break the bonds of reactants so that a reaction can proceed