Chapter 9 Production of chemicals by electrolysis Flashcards
Brine
A concentrated sodium chloride solution
Coulomb
A unit of charge, symbol C. It is the quantity of charge conveyed in one second by one ampere of current.
Electrolytic cell
A cell in which electrolysis can occur
Electrolysis
A process which produces a non-spontaneous redox reaction by the passage of electrical energy from a power supply through a conducting liquid
Electroplating
Also known as deposition, a process which uses electrolysis to deposit a layer of metal on the surface of another material.
Faraday
The charge on one mole of electrons, symbol F. One Faraday has a charge of 96500 Coulombs
Faraday’s first law of electrolysis
The mass of metal produced at the cathode is directly proportional to the electrical charge passed through the cell. It may be written as m is proportional to Q
Faraday’s second law of electrolysis
In order to produce one mole of a metal, one, two, three or another whole number of moles of electrons must be consumed.
Non-spontaneous reaction
A reaction which would not normally occur without the application of electrical energy. It is the reverse of a spontaneous reaction which produces electrical energy.
Reactive electrode
An electrode which is consumed in an electrochemical cell reaction
Semi-permeable membrane
A membrane that will only allow certain molecules or ions to pass through it
Spontaneous reaction
A reaction which occurs naturally, either in electrochemical cells or when chemicals are mixed directly. The reaction does not need to be driven by an external source of power.