Chapter 8 part 2: Bases Flashcards
What is a base?
- A base is a metal oxide/a metal hydroxide.
- Most bases are insoluble in water.
- E.g. Magnesium oxide, magnesium hydroxide, copper (II) oxide, and copper (II) hydroxide do not dissolve in water.
What is an alkali?
- An alkali is a soluble base that produces hydroxide ions (OH-) when dissolved in water.
What are the names and chemical formula(s) of some common alkalis?
- Sodium hydroxide:
Chemical formula: NaOH - Potassium hydroxide
Chemical formula: KOH - Calcium hydroxide
Chemical formula: Ca (OH)2 - Aqueous ammonia
Chemical formula: NH3
Do all alkalis produce hydroxide ions (OH-) in aqueous solutions?
- Yes, all alkalis produce hydroxide ions (OH-) in an aqueous solution.
- E.g. KOH (aq) โ> K+ (aq) + OH- (aq)
- E.g. NaOH (aq) โ> Na+ (aq) + OH- (aq)
- E.g. Ca (OH)2 (aq) โ> Ca2+ (aq) + 20H- (aq)
Does ammonia contain any metals like other alkalis?
- No, ammonia does not contain any metals like other alkalis
- NH3 (g) + H2O (l) โ>/<โ OH- (aq) + NH4+ (aq)
What are some properties of alkalis?
Alkalis:
- Have a bitter taste.
- Feel soapy.
- Conduct electricity due to the mobile ions produced when they dissolve in water.
- Turn red litmus paper blue.
What is a Alkali + acids
โ> salts + water reaction?
- Alkalis react with acids to form salts and water.
Alkali + acid โ> salt + water - E.g. Sodium hydroxide + nitric acid โ> sodium nitrate + water
NaOH (aq) + HNO3 (aq) โ> NaNO3 (aq) + H2O (l)
What is the reaction between an acid and an alkali?
- The reaction between an acid and an alkali is known as a neturalisation reaction.
- The hydrogen ions from the acid react with the hydroxide ions from the alkali to form water.
- The ionic equation for a neutralisation reaction:
H+ (aq) + OH- (aq) โ> H2O (l)
What is the reaction between an alkali and ammonia salts?
- Alkalis react with ammonium salts on heating to form salts, water and ammonia gas.
Alkali + ammonium salt โ> salt + water + ammonia - E.g. Sodium hydroxide + ammonia chloride โ> sodium chloride + water + ammonia
NaOH (aq) + NH4 Cl (aq) โ> NaCl (aq) + H2O (l) + NH3 (g) - E.g. Potassium hydroxide + ammonia sulfate โ> potassium sulfate + water + ammonia
2KOH (aq) + (NH4)2 SO4 (aq) โ> K2SO4 (aq) + 2H(square 2)O (l) + 2NH3 (g)
How can the ammonia gas produced during the reaction of an alali with an ammonium salt be identified?
- The ammonia gas produced during the reaction of an alkali with an ammonium salt can be identified using damp (moist) red litmus paper.
- Ammonia gas turns damp red litmus paper blue.
What is the factor that affects acidity?
- Acidity depends on the concentration of hydrogen ions (H+) relative to that of hydroxide ions (OH-) in a solution.
How can we tell if the solution is acidic?
- If the concentration of hydrogen ions in a solution is higher than the concentration of hydroxide ions, the solution is acidic.
What is the factor that affects alkalinity?
- Alkalinity depends on the concentration of hydroxide ions (OH-) relative to that of hydrogen ions (H+) in a solution.
How can we tell if the solution is alkaline?
- If the concentration of hydroxide ions in a solution is higher than the concentration of hydrogen ions, the solution is alkaline.
Is a neutral solution acidic/alkaline?
- In a neutral solution, the concentrations of hydrogen ions and hydroxide ions are the SAME.