Chapter 7 part 2: Stoichiometry Flashcards

1
Q

What is Stoichiometry?

A
  • Stoichiometry is the relationship between the number of moles of different substances involved in a chemical reaction.
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2
Q

What is the mole ratio?

A
  • The mole ratio can be the ratio of the amount/the number of moles of substances that are required for a complete reaction/formed at the end of the reaction.
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3
Q

How can we find the mole ratio?

A
  • The mole ratio can be determined from the Stoichiometric ratios of different substances in a balanced chemical equation
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4
Q

What are one of the functions/uses of mole ratio(s)?

A
  • The mole ratio of a substance can be used to determine the number of moles of the substances.
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5
Q

What is the volumetric analysis?

A
  • The volumetric analysis usually involves the use of 2 solutions, namely (usually) the analyte and the titrant.
  • This method is known as titration.
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6
Q

What is Titration?

A
  • Titration is the process that is a volumetric analysis that involves the use of the analyte and the titrant.
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7
Q

What is an analyte?

A
  • An analyte is a solution with an unknown concentration.
  • A fixed volume of analyte is placed into a conical flask using a pipette.
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8
Q

What is a titrant?

A
  • A titrant is a solution with a known concentration.
  • It is placed in a burette and is added to the analyte during titration.
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9
Q

What is the substance that is added into the analyte in the conical flask before the titrant is added?

A
  • An indicator is added into the analyte in the conical flask before the titrant is added
  • The indicator then changes colour when the titrant that was added has reacted completely with the analyte.
  • This shows that the titration has reached its end-point.
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10
Q

What is a limiting reactant?

A
  • A limiting reactant is the reactant that is completely used up in a reaction.
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11
Q

What is the dependent variable of the amount of product that is formed?

A
  • The amount of the product formed depends on the amount of the limiting reactant.
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12
Q

How is the limiting reactant presented?

A
  • The limiting reactant is presented in a smaller amount/has a smaller number of moles, compared to other reactants.
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13
Q

What does the mole ratio of reactants show?

A
  • The mole ratio of the reactants obtained from the chemical equation of the reaction shows the Stoichiometric ratio of reactants that should be used.
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14
Q

What happens if the reactants are not used in the correct Stoichiometric ratio?

A
  • If the reactants are not used in the correct Stoichiometric ratio, then the limiting reactant must be determined.
  • E.g. of how a reactant can be determined:
    1. 16g of sulfur with 20g of oxygen to form sulfur dioxide gas, SO2.
    (a) Write a balanced chemical equation:
  • S + O2 โ€“> SO2

(b) Calculate the number of moles of sulfur and oxygen used.
- Number of moles of sulfur
= 16/32
= 0.500 mol
- Number of moles of oxygen
= 20/(2x16)
= 20/32
= 0.625 mol

(c) Obtain the mole ratio of sulfur to oxygen from the equation and use it to determine the number of moles of reactants required.
- From the equation, 1 mol of sulfur reacts with 1 mol of oxygen.
- The number of moles of sulfur
= The number of moles of oxygen = 0.500 mol

(d) Determine the limiting reactant based on the number of moles of reactants required.
- From the mole ratio of sulfur to oxygen, 0.500 mol of oxygen is required, but 0.625 mol of oxygen is present.
- Thus, oxygen is in excess and sulfur is the limiting reactant.

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15
Q

What happens to the products in a reversible reaction?

A
  • In a reversible reaction, the products can decompose to form reactants.
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16
Q

What happens to the conversion of reactants into products when an impure reactant is used?

A
  • When an impure reactant is used, not all of the reactants are converted inot products.
17
Q

How can we represent yield?

A
  • Yield can be in the form of the mass/volume/number of moles of a substance.
18
Q

What is the theoretical yield?

A
  • the theoretical yield is the amount of product formed when all the reactants react completely in a reaction.
19
Q

What is the actual yield?

A
  • The actual yield is the actual amount of product formed in a reaction.
  • This value that is formed is always smaller than the theoretical yield.
20
Q

How can we determine the percentage yield?

A
  • The percentage yield can be determined using:
  • Percentage yield
    = Actual yield/theoretical yield x 100%
21
Q

How can we calculate the percentage purity?

A
  • We can calculate the percentage purity using mass/volume/number of moles of a substance.
22
Q

Is the number/amount of a pure substance always smaller/bigger than the amount of the same substance that is present in the reaction?

A
  • YES, the amount of a pure substance is ALWAYS smaller than the amount of the same substances present in the reaction.