chapter 8 Flashcards

1
Q

covalent bonds are a

A

sharing of electrons that form molecules

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2
Q

covalent bonds…

A

share electrons and involves only nonmetals

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3
Q

Compounds that are bonded covalently are called

A

molecular compounds

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4
Q

molecular compounds have

A

lower melting and boiling points than ionic

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5
Q

molecular compounds tend to be

A

gases or liquids at room temperature

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6
Q

molecular formula

A

Shows how many atoms of each element a molecule contains

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7
Q

double bond

A

is when atoms share two pairs of electrons (4 total)

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8
Q

triple bond

A

is when atoms share three pairs of electrons (6 total)

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9
Q

Bond Dissociation Energies…

A

The total energy required to break the bond between 2 covalently bonded atoms

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10
Q

High dissociation energy usually means

A

the chemical is relatively unreactive, because it takes a lot of energy to break it down.

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11
Q

Resonance is…

A

When more than one valid dot diagram is possible

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12
Q

The 3 Exceptions to Octet rule

A
  1. odd number of valence electrons
  2. boron and berillyum
  3. in period 3 or beyond
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13
Q

sigma bond

A

when two atomic orbitals combine to form the molecular orbital that is symmetrical along the axis connecting the nuclei

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14
Q

pi bond

A

the bonding electrons are likely to be found above and below the bond axis (weaker than sigma)

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15
Q

shared evenly

A

nonpolar covalent bond

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16
Q

shared unevenly

A

polar covalent

17
Q

electronegativity increases

A

as you go up and to the right

18
Q

diatomic defeniton

A

made of two atoms

19
Q

which atoms are diatomic?

A

Hydrogen, nitrogen, fluorine, oxygen, iodine, chlorine, bromine
Have no fear of ice cold beer

20
Q

Bond lent:

A

distance between 2 atoms where sharing is optimal and repulsion between two nuclei is negligible

21
Q

how to draw lewis structures

A
  1. Count number of valence electrons
  2. First element listed is central element, carbon always and hydrogen never
  3. Draw single bonds
  4. Assign remaining electrons to outside atoms first until octet then the central
  5. Check for octet and draw double or triple bonds as needed/resonance
22
Q

extended octet:

A

element has more than 8 electrons in lewis structure, only possible for elements period 3 and down, because they have available d’orbitals

23
Q

intramolecular bonds:

A

bonds within molecule (polar/nonplar)

24
Q

intermolecular bonds:

A

bonds between 2 molecules

25
Q

dipole-dipole

A

between 2 polar bonds

26
Q

LDF

A

between 2 nonpolar bonds

27
Q

H-bond

A

bond must have H-O, H-N, H-F

28
Q

bonds strongest to weakest

A

hydrogen bond
dipole
ldf
in large amount ldf can be stronger than dipole

29
Q

structural formula

A

chemical formula that shows the arrangement of atoms in molecules and polyatomic ions

30
Q

dispersion force

A

interaction caused y the motion of electrons

31
Q

network solid

A

substance in which all of the atoms are covalently bonded to each other

32
Q

coordinate covalent bond

A

a covalent bond in which the shared electron pair comes from only one of the atoms

33
Q

bonding orbital

A

molecular orbital that can be occupied by two electrons of a covalent bond

34
Q

sigma bond

A

symmetrical bond along the axis between the two nuclei

35
Q

VSEPR theory

A

shapes adjust so valence-electron pairs are as far apart as possible

36
Q

network solid

A

crystal in which all the atoms are covalently bonded to each other

37
Q

How do atoms achieve noble-gas electron configurations in single covalent bonds?

A

Two atoms share two electrons.