Chapter 7- Polysaccharides and Glycoconjugates Flashcards

1
Q

most carbs occur as polysaccharides, aka ____

A

glycans

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2
Q

What is a homopolysaccharide?

A

contain only 1 kind of monosaccharide unit

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3
Q

what is a heteropolysaccharide?

A

contain 2 or more monosaccharides

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4
Q

2 types of polysaccharides

A
  1. storage polysaccharides
  2. Structural polysaccharides
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5
Q

Types of storage polysaccharides

A
  • starch
  • glycogen
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6
Q

Types of structural polysaccharides

A
  • cellulose
  • agarose
  • glycosaminoglycans
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7
Q

Starch is a mixture of ____ and ______

A

alpha amylose
amylopectin

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8
Q

alpha amylose causes the starch chain to ____

A

turn

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9
Q

starch forms a _______ stabilized by H-bonds

A

left-handed helix

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10
Q

Glycogen is similar to ____

A

amylopectin

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11
Q

Why is glucose not stored in its monomeric form?

A
  1. high degree of branching
  2. Insoluble glycogen contributes to osmolarity
  3. glycogen decreases the concentration gradient
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12
Q

Glucose’s high degree of branching causes ____

A

rapid release of monosaccharide units (multiple enzymes can work at many spots simultaneously)

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13
Q

glucose’s insoluble glycogen causes contributes____

A

little to osmolarity which would cause cells to burst from water entry

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14
Q

glucose’s glycogen decreasing the concentration gradient causes ____

A

glucose to uptake in cells

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15
Q

Cellulose is a linear polymer of ____

A

D-glucose

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16
Q

Cellulose possesses _______

A

Extended conformation

17
Q

Strength of cellulose comes from ____

A

extensive H-bonding

18
Q

Cellulose strands line up into sheets which leads to:

A
  • Sheets stack on each other (added strength)
  • inter-sheet H-bonding
  • Hydrophobic molecule
19
Q

it is ____ to break down cellulose

A

hard

20
Q

Degradation of cellulose is ____ due to _____

A

very slow
tight packing and H bonding

21
Q

what is agar?

A

a complex mixture of sulfated heteropolysaccharides

22
Q

What is agarose?

A

polymer of disaccharide agarobiose

23
Q

When agarose and water is heated and cooled down:

A

it forms a double helix that traps water in the central cavity, causing the structures to form a 3D matrix/ Gel

24
Q

what are glycoconjugates?

A

sugars that are conjugated to proteins and lipids

25
Q

Functions of glycoconjugates

A
  • contribute to cell type uniqueness
  • regular cell-cel recognition and interaction
  • label proteins for localization/destruction
26
Q

All bacterial cell walls possess a strong protective polysaccharide layer called ____

A

peptidoglycan

27
Q

Lipopolysaccharide coats the outer membrane of ____

A

Gram-negative bacteria

28
Q

The composition of Lipopolysaccharide determines _____

A

the antigenicity of the bacteria

29
Q

LPS antigen structures play a role in ____

A

cell recognition evasion of the host immune system

30
Q

Gram staining interacts with the ____

A

peptidoglycan

31
Q

What is gram staining used for?

A

used as a stain to distinguish bacteria based on their cell wall composition

32
Q

Gram-positive bacteria characteristics

A
  • thick layer of peptidoglycan
  • one membrane
  • retains gram stain
33
Q

gram-negative bacteria characteristics

A
  • thinner peptidoglycan (between membranes)
  • two membranes
  • does not retain gram stain