Chapter 7: Gases, Liquids, Solids Flashcards
Kinetic Theory
Gases consist of tiny particles moving in rapid, random, straight-line motion until collision with each other or the walls of the container.
- collisions are perfectly elastic
- gas particles have mass but no volume
- distances between particles are very large compared to the size of particles themselves
Physical properties of Gases
Expand to fill containers rapid diffusion form homogenous mixtures compressible exert pressure
Diffusion
spreading of gas over a given time
due to random, rapid straight line motion until collision
Compression
Gases can be compressed due to volume being negligible
Gas Pressure
As particles move, they collide with walls = exert force
velocities of particles and frequency of collisions determine gas pressure
velocities of particles increase = pressure increase.
increase in number of particles= increase in pressure
Pressure and Volume
Volume decrease, pressure increase
reduction of vol. = increase in collisions
Pressure and Temp.
Increase temp = increase in pressure
particles have more K.E. therefore move faster therefore increase in collisions
Avagadro’s Hypothesis
equal volume of gases at the same temperature and pressure contain equal numbers of particles
volume is proportional to amount of mole of gas present
Liquid properties
particles in L are closer together than particles in Gases
Particles constantly change positions but can not travel far before collisions occur
lack of space between particles = incompressible
weak attractive forces
Solid properties
Strong attractive forces
Particles close together
Particles vibrate in fix positions
Have definite shape and volume
Changes in state
Pure substances undergo changes of state at definite temperatures
- During a phase change, the temperature of a substance remains constant because K.E. doesnt change, potential energy is changed.
Evaporation
- change from liquid to gaseous state that occurs at a temperature below the liquids boiling point
- particles that have sufficient kinetic energy escape the attractive forces of their particles and become a gas
- due to the more energetic particles escaping, the average kinetic energy of the particles in the liquid falls
- temperature of a liquid drops as evaporation happens
Vapour Pressure
Is a pressure exerted by vapour in equilibrium with its gas or liquid at a specific temperature in a closed system
- two things occurring: evaporation and condensation
- stronger attractive forces= greater K.E. required for particles to escape = lower V.P.
- Weaker attractive forces = less K.E. required for particles to escape = higher V.P.
Boiling
occurs when vapour pressure = atmospheric pressure
low atmospheric pressure = low boiling point