Chapter 7 - Alcohols, Phenols, and Thiols Flashcards

1
Q

It contain an OH (hydroxyl) group.

A

Alcohols

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2
Q

alcohol that has an OH group on a C bonded only to 1 C atom.

A

Primary (1o)

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3
Q

alcohol that has an OH group on a C bonded only to 2 C atoms.

A

Secondary (2o)

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4
Q

alcohol that has an OH group on a C bonded only to 3 C atoms.

A

Tertiary (3o)

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5
Q

True or False:

alcohols have higher boiling and melting points than hydrocarbons of comparable size and shape.

A

True

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6
Q

True or False:

Hydrogen bonds are stronger than ordinary covalent bonds.

A

False
(Weaker)

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7
Q

Proton donor

A

Bronsted-Lowry Acid

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8
Q

Proton Acceptor

A

Bronsted-Lowry Base

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9
Q

True or False:

Strong acid has strong conjugate base (vice versa)

A

False
( Strong acid has weak conjugate base (vice versa))

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10
Q

Electron-pair acceptor

A

Lewis acid

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11
Q

Electron pair donor

A

Lewis base

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12
Q

Substance that can act as an acid or as a base

A

Amphoteric

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13
Q

What type of acids are alcohols and phenols?

A

Weak acids

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14
Q

Phenols are _______ acids than alcohols

A

Stronger

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15
Q

Polar bonds that place a partial positive charge near the negative charge on an alkoxide ion stabilize the ion by what effect?

A

Inductive effect

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16
Q

p-nitrophenol has lower pKa thus, _________ acid than phenol.

A

Stronger

17
Q

Product or basicity of alcohols and phenols

A

Alkyloxonium ion

18
Q

used to prepare alkenes and is the reverse of hydration

A

Dehydration

19
Q

Rule that states that the major product has the most alkyl groups bonded to the C═C.

A

Zaitsev rule