Chapter 6 Electronic Structure Of Atoms Flashcards

1
Q

Wavelength

A

Distance between corresponding points on adjacent waves

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2
Q

Number of waves passing a given point per unit of time is

A

Frequency

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3
Q

All electromagnetic radiation travels

A

At the speed of light

3 x 10^8 m/s

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4
Q

C=

A

Wavelength x frequency

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5
Q

Energy comes in packets called

A

Quanta

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6
Q

Einstein concludes that energy is proportional to

A

Frequency

E=hv

Where H is planks constant. 6.626 E-34 J-s

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7
Q

Visible region on spectrum

A

400nm-750nm

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8
Q

Energy absorbed or emitted from electron promotion or demotion

A

E= -hcRh (1/n2 - 1/n1)

Rh is the Rydberg constant 1.097 E7

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9
Q

Equation for wavelength, h, m, v

A

Wavelength=h/mv

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10
Q

Quantum mechanics

A

Mathematical relationship between wave and particle nature of matter

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11
Q

An orbital describes

A

A spatial distribution of electron density

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12
Q

An orbital is described by a set of three

A

Quantum numbers

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13
Q

Principal quantum number

A

n

Value of n is integers greater than or equal to 1

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14
Q

Angular momentum Quantum Number

A

l

Defines the shape of the orbital

Values ranging from 0 to n-1

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15
Q

l orbital number types

A

0-s
1-p
2-d
3-f

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16
Q

Magnetic quantum number

A

m

-l to l

17
Q

Orbitals with the same value of n form a

A

She’ll

18
Q

Different orbital types within a shell

A

Sub shells

19
Q

Shape of s orbitals

A

Spherical

20
Q

Shape of p orbitals

A

Two lobes on x,y,and z axis

6

21
Q

D orbital shape

A

Four lobes on each axis with a ring

22
Q

Spin Quantum Number

A

Spin describes its magnetic field which affects its energy

Ms values are +1/2 or -1/2

23
Q

No two electrons can have the same

A

Set of Quantum numbers because no two electrons can have the same exact energy

24
Q

Hunds Rule

A

For degenerate orbitals, the lowest energy is attained when the number of electrons with the same spin is maximized

25
Q

Orbital filling exception

A

4s1 3d5 rather than 4s2 3d4