Chapter 6 Flashcards
What is the shapes of and bond angles in a molecule with two bond pairs of electrons?
bond angle- 180
shape- linear
What is the shapes of and bond angles in a molecule with three bond pairs of electrons?
bond angle- 120
shape- trigonal planar
What is the shapes of and bond angles in a molecule with four bond pairs of electrons?
bond angle- 109.5
shape- tetrahedral
What is the shapes of and bond angles in a molecule with six bond pairs of electrons?
bond angle- 90
shape- octahedral
What is the shapes of and bond angles in a molecule with three bond pairs and 1 lone pair of electrons?
bond angle- 107
shape- pyramidal
What is the shapes of and bond angles in a molecule with two bond pairs and 2 lone pairs of electrons?
bond angle- 104.5
shape- non-linear
What do lone pairs do in shape of molecules?
Repel more strongly than bonded pairs, decreasing the bond pair by 2.5 per lone pair.
What is electronegativity?
It is the ability of an atom to attract the bonding electrons in a covalent bond.
How is electronegativity affect the periodic table?
It increase across a period and decreases down the groups. Elements in the top right hand corner are the most electronegativity.
What is a polar covalent bond?
When the bonding electrons between two atoms with differing electronegativity are shared unequally.
What happens to the dipoles in symmetrical molecules?
The dipoles cancel out so there are no permanent dipoles.
What happens to the dipoles in unsymmetrical molecules?
The dipoles do not cancel each other out so the molecules has permanent dipoles and is polar.
What are the temporary dipoles?
The distribution of electrons in an atom or non-polar molecule is random, so temporary dipoles will exist - these are constantly shifting.
What are London forces?
London forces exist between all molecules and are the attraction between temporary dipoles and the induced-dipoles by cause in neighbouring species.
What are permanent dipole-dipole interactions?
Permanent dipole-dipole interactions are stronger and exist between molecules with permanent dipoles where electron distribution is less random.