Chapter 6 Flashcards

1
Q

What is the shapes of and bond angles in a molecule with two bond pairs of electrons?

A

bond angle- 180

shape- linear

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2
Q

What is the shapes of and bond angles in a molecule with three bond pairs of electrons?

A

bond angle- 120

shape- trigonal planar

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3
Q

What is the shapes of and bond angles in a molecule with four bond pairs of electrons?

A

bond angle- 109.5

shape- tetrahedral

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4
Q

What is the shapes of and bond angles in a molecule with six bond pairs of electrons?

A

bond angle- 90

shape- octahedral

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5
Q

What is the shapes of and bond angles in a molecule with three bond pairs and 1 lone pair of electrons?

A

bond angle- 107

shape- pyramidal

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6
Q

What is the shapes of and bond angles in a molecule with two bond pairs and 2 lone pairs of electrons?

A

bond angle- 104.5

shape- non-linear

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7
Q

What do lone pairs do in shape of molecules?

A

Repel more strongly than bonded pairs, decreasing the bond pair by 2.5 per lone pair.

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8
Q

What is electronegativity?

A

It is the ability of an atom to attract the bonding electrons in a covalent bond.

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9
Q

How is electronegativity affect the periodic table?

A

It increase across a period and decreases down the groups. Elements in the top right hand corner are the most electronegativity.

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10
Q

What is a polar covalent bond?

A

When the bonding electrons between two atoms with differing electronegativity are shared unequally.

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11
Q

What happens to the dipoles in symmetrical molecules?

A

The dipoles cancel out so there are no permanent dipoles.

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12
Q

What happens to the dipoles in unsymmetrical molecules?

A

The dipoles do not cancel each other out so the molecules has permanent dipoles and is polar.

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13
Q

What are the temporary dipoles?

A

The distribution of electrons in an atom or non-polar molecule is random, so temporary dipoles will exist - these are constantly shifting.

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14
Q

What are London forces?

A

London forces exist between all molecules and are the attraction between temporary dipoles and the induced-dipoles by cause in neighbouring species.

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15
Q

What are permanent dipole-dipole interactions?

A

Permanent dipole-dipole interactions are stronger and exist between molecules with permanent dipoles where electron distribution is less random.

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16
Q

What is hydrogen bonding?

A

Is the intermolecular bonding between molecules containing N, O or F with a lone pair, and the H atoms f -NH, -OH or -HF.

17
Q

What is the strongest type of intermolecular force?

A

Hydrogen bonding

18
Q

Why does ice float?

A

Ice is less dense than liquid as the H2O molecules are held further apart in the solid crystal structure by the arrangement of the hydrogen bond.

19
Q

Why does water have a high surface tension?

A

Because of the molecules on the surface experiencing unbalanced hydrogen bonding forces pulling them in.

20
Q

What is a simple molecular lattice?

A

Is the soild structure of covalently bonded molecules attracted together by intramolecular forces.