Chapter 6 Flashcards
Electromagnetic radiation
is defined as an oscillating electric and magnetic field consisting of broad regions called radio waves, microwaves, infrared waves (IR), ultraviolet (UV) rays, x-rays, and gamma (Y) rays.
E=hf
E=energy (Joules or J)
h=planck’s constants (6.6*10-34 J/s)
f=frequency (Hz or s-1)
E=hc/ t (wavelength)
E=energy (Joules or J)
h=planck’s constants (6.610-34 J/s)
c=speed of light (3.010^8 m/s)
t= wavelength (10^9 nm=1m)
c= f * t (wavelength)
c=speed of light (3.0*10^8 m/s)
t= wavelength (10^9 nm=1m)
f=frequency (Hz or s-1)
E
energy (Joules or J)
H
planck’s constants (6.6*10-34 J/s)
F
frequency (Hz or s-1)
Wavelength
units are in meters (m) and nanometers (10^9 nm=1m)
C
speed of light (3.0*10^8 m/s)
Proportions:
E is directly proportional to F (inc E, Inc F)
E & F are indirectly proportional to wavelength (inc in E & F, dec wavelength)
Constructive interference
produces a combined wave having a LARGER amplitude
Light bands are the result of interfering waves perfectly overlapping each other
Destructive interference
produce a combined wave of smaller to zero amplitude
Dark bands result from interfering waves being out of sync with each other
Converting between frequency and wavelength
nm 10^-9
pm 10^-12
Order waves and rays
gamma rays x rays uv visible spectrum ir microwave radio waves
Visible Spectrum
400-700
Violet Blue Green Yellow Orange Red
Absorption
Absorption: an electron can jump from a lower-energy (n=1) to a higher-energy (n=3) orbit by absorbing a photon of light of the same frequency as the energy difference between the orbits
Emission
When an electron falls from a higher energy (n=3) to a lower-energy (n=1) orbit, it emits a photon of light of the same frequency as the energy difference between the orbits
Rydberg Equation: WAVELENGTH
R= 1.097 X 10^7 m-1, nf
R is the constant
Nf and ni are positive whole numbers
As the difference between nf and ni increases, the difference in energy between ni and nf decreases (E and wavelength are inversely proportional), thus wavelength will increase