Chapter 6 Flashcards

(40 cards)

1
Q
  • Thermodynamics
A

o Branch of chemistry concerned with energy changes

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2
Q
  • Energy
A

o Capacity to do work

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3
Q
  • Kinetic energy
A

o Energy of motion

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4
Q
  • Potential energy
A

o Stored energy

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5
Q
  • Energy flow
A

o Energy comes from the sun

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6
Q
  • Spontaneous processes
A

o Occur without energy input

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7
Q
  • Free energy
A

o Is energy that can do work when temperature and pressure are uniform

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8
Q
  • H
A

o Enthalpy

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9
Q
  • T
A

o Absolute temperature

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10
Q
  • S
A

o Entropy

o There but unavailable

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11
Q
  • positive (delat)G
A

o Products have more free energy than reactants
o H is higher than S
o Not spontaneous
o Endergonic

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12
Q
  • Negative (delta)G
A

o Products have less free energy than reactants
o H is lower than S
o Spontaneous
o Exergonic

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13
Q
  • Activation energy
A

o Extra energy is required

o Destabilize existing bonds and initate a chemical reaction

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14
Q

Exergonic reaction’s rate depend on

A

activation energy required

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15
Q
  • Larger activation energy proceeds
A

more slowly

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16
Q
  • Rate can be increased in 2 ways
A

o Heating

o Lowering activation energy

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17
Q
  • Catalysts
A

o Substance that infuelnce chemical bonds in a way that lowers activation energy
o Do not alter the proportion of reactant turned into product

18
Q
  • ATP
A

o Energy “currency” of all cells

19
Q
  • ATP composed of
A
o	Ribose
o	Adenine
o	Chain of 3 phospates 
	Key to energy storge
	Bonds are unstable
20
Q
  • Hydrolysis of ATP
A

o Perform work

21
Q
  • 3 types of cellular work
A

o Mechanical
o Transport
o Chemical

22
Q
  • ATP Cycle
A

o ATP hydrolysis drives endergonic reactions
 Coupled reactions results in exergonic and spontaneous
o ATP not suitable for long-term energy storage

23
Q
  • Metabolism
A

o Total of all chemical reactions carried out by an organism

24
Q
  • Anabolic reactions
A

o Expend energy to build up molecules

25
- Catabolic reactions
o Harvest energy by breaking down molecules
26
- Metabolic pathways
o Series of linked reactions o Begin with specific reactant and produce an end product o Metabolic energy is captured and utilized more easily because it is released in increments
27
- Catabolic pathways
o Release energy by breaking down complex molecules into simpler compounds
28
- Anabolic pathways
o Consume energy to build complex molecules from simpler ones
29
- Enzymes
o Protein o Shape of enzyme stabilzes a temporary association between substrates o Enzyme not changed or consumed in reation
30
- Holoenzyme
o Protein and other nonpretein molecule
31
- Apoenzyme
o Protein portion of the enzyme
32
- Cofactor
o Nonprotein portion
33
- Coenzyme
o Organic cofactors |  Often vitamins
34
- Active site
o Pocket for substrate binding o Forms enzyme-substrate complex o Precise fit of substrate into active site
35
- Induced fit
o Applies stress to distort particular bond to lower activation energy
36
- Inhibitor
o Substance that binds to enzyme and decreases in it’s activity
37
- Competitive inhibitor
o Competes with substrate for active site
38
- Noncompetitive inhibitor
o Binds to enzyme at a site other than active site | o Changes shape and makes enzyme unable to bind substrate
39
- Allostreic enzymes
o Either active and inactive forms o Most noncompetitive inhitiors bind to allosteric site o Chemical on/off switch
40
- Feedback inhibition
o End-product of pathway  Binds to an allosteric site on enzyme that catalyzes first reaction in path o Shuts down pathway