Chapter 5.1 - 5.4 (Inter/intramolecular forces; states of matter) Flashcards
Intramolecular force
found within bonds between elements (atoms) within a compound
Intermolecular force
between molecules; weaker than intramolecular forces
Ionic bonds
complete transfer of electrons from one atom to the other; metal becomes a positively charged ion and the nonmetal becomes a negatively charged ion
Covalent bonds
sharing of electrons between atoms
Nonpolar covalent
when both atoms have similar electronegativity
Polar covalent
when atoms have different electronegativities; creates partial charges
Metallic bonds
occurs between metal atoms; Valence electrons are free to move through the positively charged atomic nuclei
Relative Strengths of Intramolecular Forces (weakest to strongest)
Nonpolar Covalent
Polar Covalent
Ionic
Metallic
Types of Intermolecular Forces
London dispersion forces or van der Waals (exist between all types of molecules; weakest; low boiling point) Dipole-dipole (attraction of partial charges on different polar molecules) Hydrogen bonding (partially positive hydrogen atom is attracted to partially negative atom of N, O, or F on separate molecule; strongest; high boiling point)
Melting point
temperature at which a solid becomes a liquid
Boiling point
temperature at which a liquid becomes a gas
Viscosity
how thick a liquid is (resists flow)
Surface tension
film on the surface of liquids that allows it to resist an external force
Vapor pressure
force exerted by a gas in a container (this gas can be released from a solid or liquid)
Stronger intermolecular forces =
high viscosity and surface tension; low vapor pressure
The stronger the intermolecular forces between solute (what is dissolved) and solvent (the liquid) =
the greater the solubility
the stronger the noncovalent interactions between molecules =
more energy needed to break them apart
while looking at lewis diagrams: compounds with stronger intermolecular forces, larger masses, and less branching =
higher boiling points
dipole-dipole bonds are always ______
polar
What state of matter has the smallest space between particles?
solid
What state of matter has high speed particles?
gas
What happens to the temperature during a phase change?
it doesn’t change
What happens to particles when kinetic energy is removed?
they slow down and condense